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Recent progress in water splitting and hybrid supercapacitors based on nickel-vanadium layered double hydroxides
Journal of Energy Chemistry ( IF 14.0 ) Pub Date : 2020-09-04 , DOI: 10.1016/j.jechem.2020.08.047
Josué M. Gonçalves , Paulo R. Martins , Koiti Araki , Lucio Angnes

Environmentally friendly energy sources alternatives to fossil fuels such as solar and wind are strategic for meeting the needs of an increasingly energy demanding society, despite their periodic/intermittent nature. Thus, urge the development of clean and renewable energy sources such as based on solar energy and water in a cyclic way, by photoinduced water-splitting and regeneration in fuel cells. In this context, energy storage devices such as hybrid supercapacitors become fundamental for realization of a sustainable society. In this review, the early discovery and recent advances concerning synthetic strategies, hierarchical structures, and oxygen evolution reaction (OER)/hydrogen evolution reactions (HER) catalytic performances of nickel-vanadium double hydroxides (NiV-LDHs) based nanomaterials are summarized. A discussion about the role of vanadium ions in HER/OER was also included, highlighting the recent progress in theoretical calculations in this field. Finally, some hybrid supercapacitor electrode materials based on NiV-LDHs are described, including the strategies to circumvent the parasitic oxygen evolution reaction during charge-discharge of those energy storage devices. In short, catalysts for HER/OER and hybrid supercapacitor electrode materials based on NiV-LDHs were reviewed considering their key multifunctional role in the way to a more sustainable society.



中文翻译:

基于镍钒层状双氢氧化物的水分解和混合超级电容器的最新进展

尽管具有周期性/间歇性性质,但环保的能源替代化石燃料(例如太阳能和风能)对于满足日益增长的能源需求社会的需求具有战略意义。因此,敦促通过光诱导燃料电池中的水分解和再生,循环发展基于太阳能和水的清洁和可再生能源。在这种情况下,诸如混合超级电容器之类的储能设备成为实现可持续社会的基础。在这篇综述中,总结了基于镍钒双氢氧化物(NiV-LDHs)的纳米材料的合成策略,分级结构和氧释放反应(OER)/氢释放反应(HER)催化性能的早期发现和最新进展。还讨论了钒离子在HER / OER中的作用,突出了该领域理论计算的最新进展。最后,介绍了一些基于NiV-LDHs的混合超级电容器电极材料,包括在这些储能装置充放电期间规避寄生氧释放反应的策略。简而言之,回顾了基于NiV-LDHs的HER / OER和混合超级电容器电极材料的催化剂,考虑到它们在促进可持续发展社会方面的关键多功能作用。包括在这些储能装置充放电期间规避寄生氧释放反应的策略。简而言之,对基于NiV-LDHs的HER / OER和混合超级电容器电极材料的催化剂进行了综述,考虑到它们在促进可持续发展社会方面的关键多功能作用。包括在这些储能装置充放电期间规避寄生氧释放反应的策略。简而言之,对基于NiV-LDHs的HER / OER和混合超级电容器电极材料的催化剂进行了综述,考虑到它们在促进可持续发展社会方面的关键多功能作用。

更新日期:2020-09-05
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