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Examination and Analysis of 2 Pct Mg-55 Pct Al-1.6 Pct Si-Zn Coating on Steel
Metallurgical and Materials Transactions A ( IF 2.2 ) Pub Date : 2020-09-04 , DOI: 10.1007/s11661-020-05983-y
Yisheng R. Chen

The current study was conducted to examine the microstructure of the 2 pct Mg-55 pct Al-1.6 pct Si-Zn (wt pct) coating on steel in detail and analyse the formation mechanisms of various reaction products in the coating. The coating microstructure was comprised of an α-Al dendrite framework, and an interdendritic network, occupied by a number of solidification products, which were fine Al-Zn mixtures, Mg2Si, Si, MgZn2, and lamellar MgZn2/Zn mixtures. It was found that the Al-Zn mixtures observed in the interdendritic region were the decomposition products of the high Zn α-Al components of various eutectic reactions taking place during solidification. A method was developed to differentiate the Si and Mg2Si phases optically with colour contrasts. It was found that, when Si and Mg2Si formed, they occupied the entire interdendritic spaces at the locations where they formed. Judging from the Al-Mg-Si liquidus projection, the Mg2Si phase should form first during solidification, followed by the simultaneous formation of Mg2Si and Si. On the other hand, the MgZn2 phase formed into two different morphologies, with a large blocky shape and fine precipitates embedded in the lamellar Zn/MgZn2 mixtures, both surrounded by Al-Zn mixtures. It was observed that all eutectic reactions involved the formation of an α-Al component, which formed in a divorced manner via either growing on existing dendrite arms, or sometimes as isolated islands embedded in blocky MgZn2.



中文翻译:

钢上2 Pct Mg-55 Pct Al-1.6 Pct Si-Zn涂层的检查和分析

进行当前的研究以详细检查钢上2 pct Mg-55 pct Al-1.6 pct Si-Zn(wt pct)涂层的微观结构,并分析涂层中各种反应产物的形成机理。涂层的微观结构由一个α- Al枝晶骨架和一个枝晶网络组成,被许多凝固产物占据,这些凝固产物是细小的Al-Zn混合物,Mg 2 Si,Si,MgZn 2和层状MgZn 2 / Zn混合物。发现在枝晶间区域观察到的Al-Zn混合物是凝固期间发生的各种共晶反应的高Znα - Al组分的分解产物。开发了一种区分硅和镁的方法2个Si相在光学上具有颜色对比。发现,当Si和Mg 2 Si形成时,它们在它们形成的位置处占据了整个树突间空间。从Al-Mg-Si液相线投影来看,应在凝固过程中首先形成Mg 2 Si相,然后同时形成Mg 2 Si和Si。另一方面,MgZn 2相形成两种不同的形态,具有大的块状形状,并且细微的沉淀物嵌入层状的Zn / MgZn 2混合物中,两者均被Al-Zn混合物包围。观察到所有共晶反应都涉及α- Al组分的形成,该α- Al组分通过要么生长在现有的枝晶臂上,要么有时是嵌入在块状MgZn 2中的孤立岛。

更新日期:2020-09-05
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