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Cascade 1,3-dipolar Cycloaddition/SO2 extrusion approach for the rapid synthesis of tetraaryl-substituted pyrazoles with Aggregation Induced Emission characteristics
Tetrahedron ( IF 2.1 ) Pub Date : 2020-09-03 , DOI: 10.1016/j.tet.2020.131568
Guorui Cao , Xiang Liu , Long Wang , Yanshun Li , Dawei Teng

A highly efficient strategy was developed for the straightforward synthesis of tetraaryl-substituted pyrazoles. The cascade process consists of a regioselective 1,3-dipolar cycloaddition of benzosultam-3-ylidenes with nitrile imines and a subsequent elimination of SO2. The title compounds exhibit high fluorescence quantum yields and Aggregation Induced Emission (AIE) characteristics.



中文翻译:

级联1,3-偶极环加成/ SO 2挤出方法快速合成具有聚集诱导发射特性的四芳基取代吡唑

为了直接合成四芳基取代的吡唑,开发了一种高效的策略。级联过程包括苯并苏三-3-亚胺与腈亚胺的区域选择性1,3-偶极环加成反应,然后消除SO 2。标题化合物具有高荧光量子产率和聚集诱导发射(AIE)特征。

更新日期:2020-10-12
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