This research investigated photo-Fenton enhanced in a twin-reactor for hydrogen evolution and wastewater photodegradation simultaneously. The twin-reactor, which was two coupled reactors divided by a membrane, can simultaneously photodegrade isopropanol wastewater and separate hydrogen from water splitting. Fe²⁺/Fe³⁺ pair was used as electron mediator in the twin reactor by counter-diffusing between hydrogen and photodegradation sides. Moreover, Fe³⁺ also triggered photo-Fenton reaction to enhance the degradation of organic wastewater. SrTiO₃:Rh, Pt/SrTiO₃:Rh and Ru/SrTiO₃:Rh were used for hydrogen evolution. For isopropanol degradation, P25 (TiO₂) and WO₃ were applied. The light source was simulated sunlight using 300 W Xe lamps with AM1.5 filter. Compared with the single reactor, the isopropanol removal increased 125% and hydrogen evolution was up 37% due to H₂ separation and inhibition of reverse reaction of water splitting. In the twin reactor, 95% of pure hydrogen was obtained in the hydrogen evolution side, thus saved the cost of afterward purification.

这项研究研究了在双反应器中同时增强的Fenton光分解剂用于氢气释放和废水的光降解。双反应器是由膜分开的两个耦合反应器，可以同时光降解异丙醇废水，并从水分解中分离出氢气。通过在氢和光降解侧之间反扩散，在双反应器中将Fe ²⁺ / Fe ³⁺对用作电子介体。此外，Fe ³⁺还引发光芬顿反应，以增强有机废水的降解。使用SrTiO ₃：Rh，Pt / SrTiO ₃：Rh和Ru / SrTiO ₃：Rh进行析氢。对于异丙醇降解，P25（TiO ₂）和WO_3个被应用。光源是使用带有AM1.5滤镜的300 W Xe灯模拟的阳光。与单反应器相比，由于H _2的分离和对水分解逆反应的抑制，异丙醇的去除量增加了125％，氢的释放增加了37％。在双反应器中，在析氢侧获得了95％的纯氢，因此节省了后续纯化的成本。