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The Influence of Residual Chlorine on Pt/Zeolite Y/γ-Al2O3 Composite Catalysts: Acidity and Performance
Applied Catalysis A: General ( IF 4.7 ) Pub Date : 2020-09-03 , DOI: 10.1016/j.apcata.2020.117815
Jogchum Oenema , Renée A. van Alst , Mark J. Meijerink , Jovana Zečević , Krijn P. de Jong

In previous studies H2PtCl6∙6H2O or Pt(NH3)4(NO3)2 were used to control the location of Pt nanoparticles in Zeolite/γ-Al2O3 composites for the synthesis of metal-acid bifunctional catalysts. Use of H2PtCl6∙6H2O led to Pt nanoparticles located on the γ-Al2O3 binder, in a ‘nanoscale’ intimacy with zeolite acid sites being beneficial for performance in the conversion of hydrocarbons, compared to catalysts with Pt nanoparticles located in zeolite Y (‘closest’ metal-acid intimacy) obtained by use of Pt(NH3)4(NO3)2. A side effect of using H2PtCl6∙6H2O was a higher NH3 uptake in NH3-TPD experiments, that suggested a higher acidity possibly affecting catalysis. In this study the effect of residual chlorine on Pt/Zeolite Y/γ-Al2O3 catalysts (0.1-0.6 wt.% Cl) was investigated by (pyridine) FTIR, NH3-TPD and n-alkane hydro-isomerization. The coordination of chlorine to γ-Al2O3 was observed and led to a higher NH3 uptake, but no effect of chlorine on the catalytic performance of the catalysts was detected.



中文翻译:

余氯在Pt /沸石Y的影响/γ-Al系2 ö 3复合催化剂:酸度和性能

在以前的研究ħ 2氯铂酸6 ∙6H 2 O或铂(NH 34(NO 32分别用来控制铂的位置纳米颗粒在沸石/γ-Al系2层ö 3复合材料的金属-酸官能的合成催化剂。的H有效期2氯铂酸6 ∙6H 2 O LED到位于的Pt纳米颗粒的γ-Al 2 ö 3与通过使用Pt(NH 3)获得的位于沸石Y中的Pt纳米颗粒的催化剂(“最接近的”金属-酸亲密性)相比,在“纳米级”亲密性中与沸石酸位点有利于烃的转化性能。4(NO 32。在NH 3 -TPD实验中,使用H 2 PtCl 6 ∙6H 2 O的副作用是较高的NH 3吸收,这表明较高的酸度可能会影响催化作用。在这项研究中的余氯在Pt /沸石Y的效果/γ-Al系2 ö 3种催化剂(0.1-0.6重量%的Cl)通过(吡啶)FTIR,NH研究3-TPD和构烷烃加氢异构化。氯对在γ-Al协调2 ö 3中观察到,并导致更高的NH 3的吸收,但被检测到氯对催化剂的催化性能没有影响。

更新日期:2020-09-03
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