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CO 2 utilization via methanation using 40%Ni/Ce x Cr 1-x O 2 as a novel catalyst: a comparative study of packed-bed and micro-channel reactors
Reaction Kinetics, Mechanisms and Catalysis ( IF 1.7 ) Pub Date : 2020-09-02 , DOI: 10.1007/s11144-020-01853-1
C. Wongsartsai , V. Tongnan , T. Sornchamni , N. Siri-nguan , N. Laosiripojana , M. Hartley , U. W. Hartley

A series of 40% Ni/CexCr1-xO2 catalysts with x = 0, 0.1, 0.3, 0.5, 0.9 and 1 were synthesized using one-pot hydrolysis method as catalysts for the methanation process. The reaction was carried out in a packed-bed and micro-channel reactors. 40 wt% Ni/Ce0.5Cr0.5O2 showed the best catalytic performance towards the methanation process at 270 °C, giving 92.63% of CO2 conversion and 90.53% of CH4 yield. The catalyst exhibited great stability after 50 h of time-on-stream with carbon deposition around 0.0056 mg h−1 was observed. The micro-channel reactor showed better performance than the packed-bed reactor in term of methane production rate which offered amount of methane production rate 109.1 mL min−1 gcat−1 which nearly 8 times greater than that packed-bed reactor.



中文翻译:

使用40%Ni / Ce x Cr 1-x O 2作为新型催化剂的甲烷化甲烷利用CO 2:填充床和微通道反应器的对比研究

使用一锅法水解法合成了一系列x = 0、0.1、0.3、0.5、0.9和1的40%Ni / Ce x Cr 1-x O 2催化剂作为甲烷化过程的催化剂。该反应在填充床和微通道反应器中进行。40 wt%Ni / Ce 0.5 Cr 0.5 O 2在270°C下对甲烷化过程显示出最佳的催化性能,可实现92.63%的CO 2转化率和90.53%的CH 4产率。催化剂在运行50小时后表现出很高的稳定性,碳沉积量约为0.0056 mg h -1被观测到。就甲烷产生速率而言,微通道反应器表现出比填充床反应器更好的性能,其提供的甲烷产生速率的量为109.1mL min -1 gcat -1,是填充床反应器的近8倍。

更新日期:2020-09-03
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