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Measurement and Modeling of the Solubility of Tetrafluoromethane in Either Perfluoroheptane or Perfluorodecalin
Journal of Chemical & Engineering Data ( IF 2.0 ) Pub Date : 2020-09-01 , DOI: 10.1021/acs.jced.0c00461 Rasoul Hassanalizadeh 1 , Wayne Michael Nelson 1 , Paramespri Naidoo 1 , Deresh Ramjugernath 1
Journal of Chemical & Engineering Data ( IF 2.0 ) Pub Date : 2020-09-01 , DOI: 10.1021/acs.jced.0c00461 Rasoul Hassanalizadeh 1 , Wayne Michael Nelson 1 , Paramespri Naidoo 1 , Deresh Ramjugernath 1
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Novel isothermal phase equilibrium data were measured, via the static analytic (SA) and static synthetic (SS) techniques, for the binary mixtures of tetrafluoromethane with either perfluoroheptane or perfluorodecalin. The experimental data were correlated using the Peng–Robinson equation of state using either the classical or the Wong–Sandler mixing rules. For both binary systems, the models provide an excellent fit to the data and the Wong–Sandler mixing rule marginally outperformed the classical mixing rule. The uncertainty of the pressure, temperature, and average liquid- and vapor-phase compositions for the SA apparatus were 0.01 MPa, 0.09 K, and 0.012 and 0.0014, respectively. The uncertainty of the pressure, temperature, and average liquid-phase composition for the SS apparatus were 0.01 MPa, 0.07 K, and 0.009, respectively.
中文翻译：
四氟甲烷在全氟庚烷或全氟萘烷中的溶解度的测量和建模
通过静态分析（SA）和静态合成（SS）技术，测量了四氟甲烷与全氟庚烷或全氟萘烷的二元混合物的新型等温相平衡数据。使用Peng-Robinson状态方程，使用经典或Wong-Sandler混合规则，将实验数据关联起来。对于这两种二进制系统，模型都非常适合数据，并且Wong-Sandler混合规则略胜于经典混合规则。SA设备的压力，温度以及平均液相和气相组成的不确定度分别为0.01 MPa，0.09 K，0.012和0.0014。SS设备的压力，温度和平均液相组成的不确定度分别为0.01 MPa，0.07 K和0.009。
更新日期：2020-10-08
中文翻译：
四氟甲烷在全氟庚烷或全氟萘烷中的溶解度的测量和建模
通过静态分析（SA）和静态合成（SS）技术，测量了四氟甲烷与全氟庚烷或全氟萘烷的二元混合物的新型等温相平衡数据。使用Peng-Robinson状态方程，使用经典或Wong-Sandler混合规则，将实验数据关联起来。对于这两种二进制系统，模型都非常适合数据，并且Wong-Sandler混合规则略胜于经典混合规则。SA设备的压力，温度以及平均液相和气相组成的不确定度分别为0.01 MPa，0.09 K，0.012和0.0014。SS设备的压力，温度和平均液相组成的不确定度分别为0.01 MPa，0.07 K和0.009。
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