Visible-Light-Mediated Aminoquinolate Diarylboron-Catalyzed Metal-Free Hydroxylation of Organoboronic Acids under Air and Room Temperature,ACS Sustainable Chemistry & Engineering

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Visible-Light-Mediated Aminoquinolate Diarylboron-Catalyzed Metal-Free Hydroxylation of Organoboronic Acids under Air and Room Temperature
ACS Sustainable Chemistry & Engineering ( IF 7.1 ) Pub Date : 2020-09-01 , DOI: 10.1021/acssuschemeng.0c05121
Lanfeng Wei ₁ , Jinli Zhang _{1,

2} , Liang Xu ₁

Affiliation

An aminoquinolate diarylboron-catalyzed photoredox hydroxylation process has been realized herein. Via aerobic oxidation of organoboronic acid derivatives under air, a variety of functionalized phenols can be obtained in good to excellent yields. This protocol does not require the use of metallic (photo)catalysts and oxidants. It is also distinguished by green and mild conditions, simplicity of operation, and broad substrate scope.

中文翻译：

空气和室温下可见光介导的氨基喹诺酮酯二芳基硼催化的有机硼酸的无金属羟基化反应

本文已经实现了氨基喹啉酸酯二芳基硼催化的光氧化还原羟基化方法。通过在空气下对有机硼酸衍生物进行有氧氧化，可以以良好或优异的收率获得各种官能化的酚。该协议不需要使用金属（光）催化剂和氧化剂。它还具有绿色和温和的条件，操作简单和广泛的基材范围。

更新日期：2020-09-21

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