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Microwave Assisted Synthesis of Covalent Organic Frameworks: A Review.
ChemSusChem ( IF 7.5 ) Pub Date : 2020-09-01 , DOI: 10.1002/cssc.202001865
Borja Díaz de Greñu 1 , Juan Torres 1 , Javier García-González 1 , Sara Muñoz-Pina 1 , Ruth de Los Reyes 2 , Ana M Costero 3 , Pedro Amorós 4 , Jose V Ros-Lis 1
Affiliation  

Covalent organic frameworks (COFs) are relatively recent materials. They have received great attention due to their interesting properties. However, the application of microwaves in their synthesis, despite its advantages such as faster and more reproducible processes, is a minority. Herein, a comprehensive compilation of the research results published in the microwave‐assisted synthesis (MAS) of COFs is presented. This review includes articles of 2D and 3D COFs prepared using microwaves as source of energy. The articles have been classified depending on the functional groups including boronate ester, imines, enamines, azines, and triazines, among others. It compiles the main parameters of synthesis and characteristics of the materials together with some general issues related with COFs and microwaves. Additionally, current and future perspectives of the topic have been discussed.

中文翻译:

微波辅助合成共价有机骨架:综述。

共价有机框架(COF)是相对较新的材料。它们因其有趣的特性而受到了极大的关注。然而,尽管微波具有诸如更快和更可再现的过程的优点,但是在微波合成中的应用却很少。本文介绍了在COF的微波辅助合成(MAS)中发表的研究结果的综合汇编。该评论包括使用微波作为能源制备的2D和3D COF的文章。根据包括硼酸酯,亚胺,烯胺,嗪和三嗪的官能团对制品进行了分类。它汇编了材料的合成的主要参数和材料的特性,以及与COF和微波有关的一些一般性问题。另外,
更新日期:2020-09-01
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