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Effects of sintering additives on hot corrosion behavior of γ-Y2Si2O7 ceramics in Na2SO4+V2O5 molten salt
Journal of the European Ceramic Society ( IF 5.8 ) Pub Date : 2020-09-02 , DOI: 10.1016/j.jeurceramsoc.2020.08.068
Xingyu Fan , Runjun Sun , Jie Dong , Liang Wei , Qiushi Wang

Dense γ-Y2Si2O7 ceramics were prepared by moulding and sintering of pure γ-Y2Si2O7 powders synthesized by adding various additives. Effects of sintering additives on hot corrosion behavior of γ-Y2Si2O7 ceramics in Na2SO4 + V2O5 molten salts were systematically investigated. Chemical kinetics of corrosion process was also calculated to illuminate the influence of different additives on chemical stability. Results showed that corrosion reaction started at grain boundary due to the loose microscopic network. When the intercrystalline glass phase was completely etched, the molten salts began to contact Y2Si2O7, forming NaY9Si6O26 and YVO4. Compared with Li2O and MgO, intercrystalline glass phase formed by Al2O3 additive had the most compact microscopic network structure, leading to the best chemical stability. Apparent activation energy for hot corrosion reaction of γ-Y2Si2O7 ceramics in pure Na2SO4, Na2SO4 + 5 wt% V2O5, Na2SO4 + 10 wt% V2O5, Na2SO4 + 15 wt% V2O5 molten salts was calculated to be 408.16, 373.60, 310.62, and 249.63 kJ/mol, respectively.



中文翻译:

上的热腐蚀行为烧结添加剂的影响γ-Y 2的Si 2个ö 7陶瓷中的Na 2 SO 4 + V 2 ø 5熔融盐

密γ-Y 2的Si 2个ö 7陶瓷的通过模制和纯γ-Y的烧结制备2的Si 2成ö 7加入各种添加剂合成的粉末。上的热腐蚀行为烧结添加剂的影响γ-Y 2的Si 2个ö 7陶瓷中的Na 2 SO 4 + V 2 ø 5对熔融盐进行了系统的研究。还计算了腐蚀过程的化学动力学,以阐明不同添加剂对化学稳定性的影响。结果表明,由于疏松的微观网络,腐蚀反应开始于晶界。当晶间玻璃相被完全蚀刻时,熔融盐开始接触Y 2 Si 2 O 7,形成NaY 9 Si 6 O 26和YVO 4。与Li 2 O和MgO相比,Al 2 O 3形成的晶间玻璃相添加剂具有最紧凑的微观网络结构,从而具有最佳的化学稳定性。对于γ-Y的热腐蚀反应表观活化能2的Si 2个ö 7在纯的Na陶瓷2 SO 4,钠2 SO 4 + 5重量%的V 2 ø 5,钠2 SO 4 + 10重量%的V 2 ø 5,计算出Na 2 SO 4 + 15 wt%V 2 O 5熔融盐分别为408.16、373.60、310.62和249.63 kJ / mol。

更新日期:2020-10-30
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