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Organosilicon ethers of ricinoleic acid
Russian Chemical Bulletin ( IF 1.7 ) Pub Date : 2020-07-01 , DOI: 10.1007/s11172-020-2913-5
N. P. Shapkin , I. G. Khalchenko , N. V. Maslova , V. V. Gribova , V. G. Savchenko

Interaction of vinyl trichlorosilane with sodium salt of ricinoleic acid is investigated. It is established that the composition and structure of silicon-containing ethers depends on the content of crystallization water in sodium ricinoleate, and the concentration and nature of solvent. Thus, in the case of a mixture of absolute alcohol with ether and low content of crystallization water, the reaction proceeds by hydroxyl of alcohol to form salt-like compounds containing silicon. In the case of a salt with a high content of crystallization water, the reaction proceeds along two reaction centers with the formation of ether and ester simultaneously. The composition and structure of the obtained compounds were established using elemental analysis, IR, 1H, 13C NMR spectroscopy, and gel chromatography. It is proposed to use prepared organosilicon ethers of ricinoleic acid as additives to motor oils instead of castor oil.

中文翻译:

蓖麻油酸有机硅醚

研究了乙烯基三氯硅烷与蓖麻油酸钠盐的相互作用。确定含硅醚的组成和结构取决于蓖麻油酸钠中结晶水的含量,以及溶剂的浓度和性质。因此,在无水醇与醚和低含量结晶水的混合物的情况下,反应通过醇的羟基进行,形成含硅的盐状化合物。在结晶水含量高的盐的情况下,反应沿着两个反应中心进行,同时形成醚和酯。所得化合物的组成和结构使用元素分析、IR、1H、13C NMR光谱和凝胶色谱法确定。
更新日期:2020-07-01
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