The theory of Watterson and White (J Chem Soc Faraday Trans II, 77: 1115, 1981) on the primary electroviscous effect in a dilute suspension of charged spherical colloidal particles in an electrolyte solution is extended to cover the case where liquid slip occurs on the particle surface on the basis of the Navier boundary condition suitable for a hydrophobic surface. The general expressions for the effective viscosity and the primary electroviscous coefficient of the suspension as well as their low-zeta potential approximate expressions are derived. Graphical abstract Primary electroviscous coefficient Primary electroviscous coefficient

中文翻译：

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带滑动面的带电球形胶体颗粒稀悬浮液中的初级电粘性效应

Watterson 和 White (J Chem Soc Faraday Trans II, 77: 1115, 1981) 关于带电球形胶体颗粒在电解质溶液中的稀悬浮液中的主要电粘性效应的理论扩展到涵盖液体滑移发生在电解质溶液中的情况。基于适用于疏水表面的 Navier 边界条件的粒子表面。推导了悬浮液的有效粘度和初级电粘性系数的一般表达式及其低zeta电位近似表达式。图形摘要 初级电粘系数 初级电粘系数