Cover Feature: Dynamic PdII/CuI Multimetallic Assemblies as Molecular Models to Study Metal–Metal Cooperation in Sonogashira Coupling (Chem. Eur. J. 53/2020),Chemistry - A European Journal

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Cover Feature: Dynamic PdII/CuI Multimetallic Assemblies as Molecular Models to Study Metal–Metal Cooperation in Sonogashira Coupling (Chem. Eur. J. 53/2020)
Chemistry - A European Journal ( IF 3.9 ) Pub Date : 2020-09-01 , DOI: 10.1002/chem.202003331
Orestes Rivada‐Wheelaghan _{1,

2} , Aleix Comas‐Vives ₃ , Robert R. Fayzullin ₄ , Agustí Lledós ₃ , Julia R. Khusnutdinova ₁

Affiliation

Metal–metal cooperation plays a crucial role in synergistic catalysis including C−C bond coupling. This work reports dynamic Pd/Cu assemblies as models to study individual steps of Sonogashira coupling. This study reveals the importance of rearrangements of the highly dynamic multimetallic assemblies (represented as constellations in this cover image) at the various steps of alkyne activation and transmetalation. More information can be found in the Full Paper by A. Lledós, J. R. Khusnutdinova, et al. on page 12168.

中文翻译：

封面人物：动态PdII / CuI多金属组件作为研究Sonogashira联轴器中金属-金属配合的分子模型（Chem。Eur。J. 53/2020）

金属间的合作在包括C-C键耦合在内的协同催化中起着至关重要的作用。这项工作报告动态Pd / Cu组件作为模型来研究Sonogashira耦合的各个步骤。这项研究揭示了在炔烃活化和过渡金属化的各个步骤中重排高动态多金属组件（在此封面图像中表示为星座图）的重要性。可以在A.Lledós，J。R. Khusnutdinova等人的《全文》中找到更多信息。在第12168页。

更新日期：2020-09-21

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