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Removal of 2,4-dichlorophenoxyacetic acid from aqueous samples using electrospun polyacrylonitrile nanofiber-based supported liquid membrane transport
Journal of the Iranian Chemical Society ( IF 2.2 ) Pub Date : 2020-09-01 , DOI: 10.1007/s13738-020-02048-0
Malihe Mir , Mir Mahdi Zahedi , Seied Mahdi Pourmortazavi

In this work, a simple supported liquid membrane transport strategy is applied to remove of the dichlorophenoxyacetic acid (2,4-D) from water samples as important agricultural pesticides. Here, the electrospun polyacrylonitrile (PAN) nanofiber-based sheet has been used in the SLM process as new support. The optimal SLM transport working parameters were found to be pH = 1 and NaCl solution of 2 M for feed phase, dichloromethane as solvent of liquid membrane and pH = 14 and NaCl solution of 2 M for receiving phase. The stirring speed, time and temperature of SLM and the interference effect for 2,4-D transport have been studied and optimized. We find that the thickness of nano-electrospun PAN sheet as support of the liquid membrane has important effect on decreasing the time of transport. Under the same working conditions, this nano-based SLM method shows significant enhancement for removing efficiency and rate of 2,4-D rather than PAN microfiltration flat sheet as support material.



中文翻译:

使用静电纺丝聚丙烯腈纳米纤维为载体的液膜传输方法从水性样品中去除2,4-二氯苯氧基乙酸

在这项工作中,采用了一种简单的支持性液膜运输策略,以从水样中去除作为重要农业农药的二氯苯氧基乙酸(2,4-D)。在这里,电纺聚丙烯腈(PAN)纳米纤维基片材已在SLM工艺中用作新的载体。发现最佳的SLM传输工作参数是:进料相的pH = 1和2 M的NaCl溶液,液膜的溶剂是二氯甲烷,接收相的pH = 14和2 M的NaCl溶液。研究和优化了SLM的搅拌速度,时间和温度以及对2,4-D传输的干扰作用。我们发现,以纳米电纺PAN片为支撑液膜的厚度对减少运输时间具有重要影响。在相同的工作条件下

更新日期:2020-09-01
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