Molten Salt Synthesis of an Open-Frame Aluminum Phosphate Ba3Al2P4O16 with a Rare-Pyramidal AlO5 Group.,Inorganic Chemistry

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Molten Salt Synthesis of an Open-Frame Aluminum Phosphate Ba3Al2P4O16 with a Rare-Pyramidal AlO5 Group.
Inorganic Chemistry ( IF 4.3 ) Pub Date : 2020-08-31 , DOI: 10.1021/acs.inorgchem.0c01566
Meihong Duan _{1,

2} , Bo Kong ₃ , Rukang Li _{1,

2}

Affiliation

A new open-frame aluminophosphate, Ba₃Al₂P₄O₁₆, was synthesized by a high-temperature flux method. Ba₃Al₂P₄O₁₆ features discrete [Al₄P₈O₃₂]_∞^12– chains with rare square-pyramidal AlO₅ groups adopted. Especially, this pyramidal AlO₅ group acts as an ideal “plane builder” or “vacancy inducer” to construct open-frame structures compared with an ordinary trigonal-bipyramidal AlO₅ group.

中文翻译：

带有稀有金字塔形AlO5基团的开放骨架磷酸铝Ba3Al2P4O16的熔融盐合成。

通过高温助熔剂法合成了一种新型的开放骨架铝磷酸盐Ba ₃ Al ₂ P ₄ O ₁₆。的Ba ₃的Al ₂ P ₄ ø ₁₆设有离散[铝₄ P ₈ ø ₃₂ ] _∞^12-链与稀有四方锥的AlO _5个通过基团。特别地，与普通的三角-双锥体AlO ₅基团相比，该金字塔状的AlO ₅基团充当构建开放框架结构的理想“平面助剂”或“空位诱导剂” 。

更新日期：2020-09-21

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