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Molten Salt Synthesis of an Open-Frame Aluminum Phosphate Ba3Al2P4O16 with a Rare-Pyramidal AlO5 Group.
Inorganic Chemistry ( IF 4.3 ) Pub Date : 2020-08-31 , DOI: 10.1021/acs.inorgchem.0c01566
Meihong Duan 1, 2 , Bo Kong 3 , Rukang Li 1, 2
Affiliation  

A new open-frame aluminophosphate, Ba3Al2P4O16, was synthesized by a high-temperature flux method. Ba3Al2P4O16 features discrete [Al4P8O32]12– chains with rare square-pyramidal AlO5 groups adopted. Especially, this pyramidal AlO5 group acts as an ideal “plane builder” or “vacancy inducer” to construct open-frame structures compared with an ordinary trigonal-bipyramidal AlO5 group.

中文翻译:

带有稀有金字塔形AlO5基团的开放骨架磷酸铝Ba3Al2P4O16的熔融盐合成。

通过高温助熔剂法合成了一种新型的开放骨架铝磷酸盐Ba 3 Al 2 P 4 O 16。的Ba 3的Al 2 P 4 ø 16设有离散[铝4 P 8 ø 32 ] 12-链与稀有四方锥的AlO 5个通过基团。特别地,与普通的三角-双锥体AlO 5基团相比,该金字塔状的AlO 5基团充当构建开放框架结构的理想“平面助剂”或“空位诱导剂” 。
更新日期:2020-09-21
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