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Solvent-Induced Reversible Spin-Crossover in a 3D Hofmann-Type Coordination Polymer and Unusual Enhancement of the Lattice Cooperativity at the Desolvated State.
Inorganic Chemistry ( IF 4.3 ) Pub Date : 2020-08-31 , DOI: 10.1021/acs.inorgchem.0c02240 Dibya Jyoti Mondal 1 , Subhadip Roy 1, 2 , Jyoti Yadav 1 , Matthias Zeller 3 , Sanjit Konar 1
Inorganic Chemistry ( IF 4.3 ) Pub Date : 2020-08-31 , DOI: 10.1021/acs.inorgchem.0c02240 Dibya Jyoti Mondal 1 , Subhadip Roy 1, 2 , Jyoti Yadav 1 , Matthias Zeller 3 , Sanjit Konar 1
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The new 3D Hofmann-type coordination polymer [Fe(dpyu){Pt(CN)4}]·9H2O [dpyu = 1,3-di(pyridin-4-yl)urea] exhibits reversible interchange between two- and one-step spin-crossover behavior, associated with desorption/resorption of lattice water molecules. Solvent water removal also induces an increase of the spin-transition temperature, indicating strong lattice cooperativity, observed for the first time in a 3D Hofmann-type coordination polymer.
中文翻译：
溶剂诱导的3D Hofmann型配位聚合物中的可逆自旋交叉和非溶剂化状态下晶格协同性的异常增强。
新型3D霍夫曼型配位聚合物[Fe（dpyu）{Pt（CN）4 }]·9H 2 O [dpyu = 1,3-二（吡啶-4-基）脲]在2和1之间可逆交换步旋转交叉行为，与晶格水分子的解吸/再吸收有关。除去溶剂水还引起自旋转变温度的升高，表明在3D霍夫曼型配位聚合物中首次观察到强的晶格协同作用。
更新日期：2020-09-21
中文翻译：
溶剂诱导的3D Hofmann型配位聚合物中的可逆自旋交叉和非溶剂化状态下晶格协同性的异常增强。
新型3D霍夫曼型配位聚合物[Fe（dpyu）{Pt（CN）4 }]·9H 2 O [dpyu = 1,3-二（吡啶-4-基）脲]在2和1之间可逆交换步旋转交叉行为，与晶格水分子的解吸/再吸收有关。除去溶剂水还引起自旋转变温度的升高，表明在3D霍夫曼型配位聚合物中首次观察到强的晶格协同作用。
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