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Improved CdS quantum dot distribution on a TiO2 photoanode by an atomic-layer-deposited ZnS passivation layer for quantum dot-sensitized solar cells
Solar Energy Materials and Solar Cells ( IF 6.3 ) Pub Date : 2020-08-31 , DOI: 10.1016/j.solmat.2020.110753
Eun Sun Jung , Muhammad Abdul Basit , Muhammad Awais Abbas , Ijaz Ali , Dae Woong Kim , Young Min Park , Jin Ho Bang , Tae Joo Park

An ultrathin (<~0.5 nm) ZnS interfacial passivation layer (IPL) was produced by atomic layer deposition in order to improve the performance of CdS quantum-dot (QD) sensitized solar cells. The mutable role of the top ZnS IPL, deposited after QD sensitization, enhanced light absorbance by acting as an anti-reflective coating resulting in increased photocurrent. The bottom ZnS IPL deposited on the TiO2 photoanode before QD sensitization led to a uniform distribution of smaller-sized QD microaggregates by modification of the surface energy of TiO2, which improved the photo-generated charge carrier injection from QD to TiO2. Furthermore, both ZnS IPLs have roles as the recombination barrier layer. Consequently, the photoconversion efficiency was enhanced by approximately 15% and 30% in cells with top and bottom ZnS IPLs, respectively.



中文翻译:

原子层沉积的ZnS钝化层改善了TiO 2光电阳极上CdS量子点的分布,用于量子点敏化太阳能电池

为了提高CdS量子点(QD)敏化太阳能电池的性能,通过原子层沉积生产了超薄(<〜0.5 nm)ZnS界面钝化层(IPL)。QD敏化后沉积的顶部ZnS IPL的可变作用通过充当抗反射涂层而增加了光吸收,从而增强了光吸收。QD敏化之前沉积在TiO 2光电阳极上的底部ZnS IPL通过改变TiO 2的表面能导致较小尺寸的QD微聚集体均匀分布,从而改善了从QD向TiO 2的光生载流子注入。此外,两个ZnS IPL都具有重组阻挡层的作用。因此,在具有顶部和底部ZnS IPL的电池中,光转换效率分别提高了约15%和30%。

更新日期:2020-08-31
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