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Enhanced effect of OMMT and KH-Al 2 O 3 on polyurethane composite mechanical properties
Journal of Polymer Research ( IF 2.6 ) Pub Date : 2020-08-31 , DOI: 10.1007/s10965-020-02269-0
Yufei Chen , Yulong Liu , Chunyan Yue , Chengjun Teng , Simin Chen

Sodium montmorillonite (MMT) was modified by octadecyl trimethyl ammonium chloride (OTAC) via cation exchange to obtain organo-montmorillonite (OMMT), Al2O3 was treated by KH-550 (3-Aminopropyltriethoxysilane) to get KH-Al2O3. The polyurethane elastomer (PUE) was synthesized with 4,4′-diphenylmethane diisocyanate (MDI), polypropylene glycol (PPG) and 1,4-butanediol (BDO) as the raw materials. And then, OMMT/KH-Al2O3/PUE composite was prepared by the prepolymer method; PUE was the matrix, OMMT and KH-Al2O3 were reinforcements. The micro-morphology and mechanical properties of OMMT/KH-Al2O3/PUE composites were measured and analyzed. The results of FT-IR and XRD showed that OTAC had been introduced into MMT layer and the layer spacing of OMMT had increased. The KH-550 had successfully grafted to the surface of Al2O3 to obtain KH-Al2O3. The TEM results demonstrated the interaction between OMMT and KH-Al2O3, weakening the interaction between the same molecules and the OMMT sheet was further peeled off. The SEM images displayed that a specific ratio of OMMT and KH-Al2O3 had excellent dispersion in the PUE matrix. The mechanical properties of OMMT/KH-Al2O3/PUE composites were significantly better than those of OMMT/PUE and KH-Al2O3/PUE composite. The maximum tensile strength, elongation at break and tensile strength at break are 21.82 MPa, 668% and 19.98 MPa, respectively, which were 43.8%, 29.2% and 36.8% higher than that of PUE matrix, when the content of inorganic components was 3 wt% and the mass rate of OMMT to KH-Al2O3 was 1:1. This composite material is a kind of excellent polyurethane elastomer and widely is maybe used in mechanical accessories, pipe, mining and metallurgy industries.



中文翻译:

OMMT和KH-Al 2 O 3对聚氨酯复合材料力学性能的增强作用

钠蒙脱石(MMT)通过改性十八烷基三甲基氯化铵(OTAC)通过阳离子交换以获得有机蒙脱土,铝2 ö 3是由KH-550(3-氨基丙基)处理,以得到KH-Al系2 ö 3。以4,4'-二苯基甲烷二异氰酸酯(MDI),聚丙二醇(PPG)和1,4-丁二醇(BDO)为原料合成了聚氨酯弹性体(PUE)。然后,通过预聚物法制备了OMMT / KH-Al 2 O 3 / PUE复合材料。PUE是基质,OMMT和KH-Al 2 O 3是增强剂。OMMT / KH-Al 2 O 3的微观形貌和力学性能/ PUE复合材料进行了测量和分析。FT-IR和XRD结果表明,OTAC已引入MMT层,OMMT的层间距增加。KH-550成功地接枝到Al 2 O 3的表面上以获得KH-Al 2 O 3。TEM结果表明,OMMT与KH-Al 2 O 3相互作用,削弱了相同分子之间的相互作用,使OMMT片进一步剥离。SEM图像显示特定比例的OMMT和KH-Al 2 O 3在PUE基质中具有优异的分散性。OMMT / KH-Al 2 O 3的力学性能/ PUE复合材料明显优于OMMT / PUE和KH-Al 2 O 3 / PUE复合材料。当无机组分含量为3时,最大抗张强度,断裂伸长率和断裂抗张强度分别为21.82 MPa,668%和19.98 MPa,分别比PUE基体高43.8%,29.2%和36.8%。 OMMT对KH-Al 2 O 3的质量比为1:1。这种复合材料是一种优良的聚氨酯弹性体,可广泛用于机械配件,管道,采矿和冶金行业。

更新日期:2020-08-31
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