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Dissipation of Herbicide Methiozolin and Its Metabolites in Aerobic Sediment-Water Systems.
Bulletin of Environmental Contamination and Toxicology ( IF 2.7 ) Pub Date : 2020-08-31 , DOI: 10.1007/s00128-020-02976-w
Jong-Hwan Kim 1, 2 , Jong-Su Seo 1 , Ji-Young An 1 , Young-Sang Kwon 1 , Ki-Hwan Hwang 3 , Suk-Jin Koo 3 , Jeong-Han Kim 4
Affiliation  

Methiozolin is a novel herbicide for controlling annual bluegrass. After applying 14C labelled methiozolin in two sediment (clay loam and sand)-water systems under aerobic conditions, its distribution, half-life, and metabolites within 300 days were investigated. The mass balance ranged within 92.0%–104.4% of applied radioactivity (AR). Radioactivity in the water declined sharply from 94.4% to 0.5% AR, while in the sediment it increased to 83.9% AR at 14 days before declining to 9.1% AR. The volatiles were minimal (< 0.5% AR), and the evolved labelled CO2 accounted for up to ~ 33.4% AR. From Radio-HPLC analysis, labelled methiozolin in water decreased from 108.9% to 0% AR, while a maximum of 15.1% AR remained in the sediment at the end. Eight metabolites were detected, all at minor levels and accounting for < 5.5% AR. The half-life of labelled methiozolin in the total sediment–water systems were 50.7 and 38.7 days for clay loam and sand, respectively.



中文翻译:

除草剂甲硫唑啉及其代谢物在好氧沉积物-水系统中的耗散。

甲硫唑啉是控制一年生禾草的新型除草剂。在好氧条件下,在两种沉积物(粘土壤土和沙子)-水系统中施用14 C标记的甲硫唑啉后,研究了其在300天内的分布,半衰期和代谢产物。质量平衡范围为所应用放射性(AR)的92.0%至104.4%。水中的放射性从94.4%的AR急剧下降到0.5%的AR,而沉积物中的放射性在14天前增加到83.9%的AR,然后下降到9.1%的AR。挥发物极少(<0.5%AR),并且释放出标记的CO 2占AR的〜33.4%。通过放射-HPLC分析,水中的标记甲硫唑啉从108.9%降至AR的0%,而在沉积物中最后最多保留了15.1%的AR。检测到8种代谢物,全部处于次要水平,占AR的<5.5%。黏土壤土和沙子在全部沉积物-水系统中标记的甲硫唑啉的半衰期分别为50.7天和38.7天。

更新日期:2020-08-31
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