Recent advances in transition metal migration involving reactions,Organic Chemistry Frontiers

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Recent advances in transition metal migration involving reactions
Organic Chemistry Frontiers ( IF 4.6 ) Pub Date : 2020-08-29 , DOI: 10.1039/d0qo00558d
Xu Dong _{1,

2,

3,

4} , Hui Wang _{5,

6,

7,

8} , Hui Liu _{1,

2,

3,

4} , Fagang Wang _{1,

2,

3,

4}

Affiliation

Numerous elegant methodologies involving transition-metal migration processes have received increasing attention and they have gradually developed into significant synthetic tools in the past few decades. These strategies provide novel ways to build a carbon–metal bond at a new position, where it may not be facile or straightforward to introduce a metal atom. Hence, metal-migration reactions exhibit attractive practicability in synthetic organic chemistry. This review gives an up-to-date overview of catalytic methodologies involving metal-migration processes, which are sorted into categories such as 1,2- to 1,5- and 1,7-Pd migration, 1,3- to 1,5-Rh migration, 1,4- and 1,5-Fe migration, and so on. For most of these transformations, plausible mechanisms are demonstrated elaborately. Clarification of these processes is a key point for understanding metal-migration involving reactions and developing new high-performance methodologies.

中文翻译：

涉及反应的过渡金属迁移的最新进展

涉及过渡金属迁移过程的许多优雅的方法论日益受到关注，并且在过去的几十年中已逐渐发展成为重要的合成工具。这些策略提供了在新位置建立碳-金属键的新颖方法，在该位置上引入金属原子可能不容易也不容易。因此，金属迁移反应在合成有机化学中显示出有吸引力的实用性。这篇综述对涉及金属迁移过程的催化方法进行了最新概述，这些方法被归类为1，2-到1,5-和1,7-Pd迁移，1,3-到1迁移。 5-Rh迁移，1,4-和1,5-Fe迁移等。对于大多数这些转换，都将详细说明合理的机制。

更新日期：2020-09-11

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