Accelerated ageing reactions: towards simpler, solvent-free, low energy chemistry,Green Chemistry

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Accelerated ageing reactions: towards simpler, solvent-free, low energy chemistry
Green Chemistry ( IF 9.3 ) Pub Date : 2020-08-28 , DOI: 10.1039/d0gc02264k
Igor Huskić _{1,

2,

3,

4} , Cameron B. Lennox _{1,

2,

3,

4} , Tomislav Friščić _{1,

2,

3,

4}

Affiliation

We provide an overview of chemical transformations that proceed spontaneously, by mixing of initially solid reactants, and are accelerated and/or directed through gentle stimuli in the form of mild heating, exposure to diverse gas or vapour environments, brief mechanical milling, and/or the presence of catalysts. This broad overview illustrates how such accelerated ageing (AA) reactions could provide a route to develop operationally simple, as well as safe, inexpensive and materials- and energy-efficient processes for the environmentally-friendly synthesis of diverse organic and metal–organic materials and molecules.

中文翻译：

加速老化反应：实现更简单，无溶剂，低能耗的化学反应

我们提供了化学转化的概述，这些化学转化通过混合最初的固体反应物而自发进行，并通过以温和加热，暴露于多种气体或蒸气环境，短暂的机械研磨和/或形式的温和刺激而加速和/或定向催化剂的存在。广泛的概述说明了这种加速老化（AA）反应如何为开发操作简便，安全，廉价，材料和能源效率高的方法，以环保合成各种有机和金属有机材料以及分子。

更新日期：2020-09-21

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