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Synthesis and comparative investigation of adsorption capability and photocatalytic activities of WO3 and W18O49
Materials Science and Engineering: B ( IF 3.6 ) Pub Date : 2020-08-28 , DOI: 10.1016/j.mseb.2020.114724
Yaru Shang , Xiaohu Cheng , Ruixia Shi , Qian Ma , Yingzi Wang , Ping Yang

The adsorption experimental results show that W18O49 with oxygen vacancies not only has faster adsorption rates for MB but also has larger adsorption capacities than WO3. Besides, the maximum adsorption capacity of urchin-like W18O49 (375.94 mg/g) is about 2.76 times of WO3 (136.25 mg/g). However, photocatalytic results revealed that WO3 has better photocatalytic degradation ability than W18O49. Generally, the adsorption efficiency of urchin-like W18O49 (70.01%) is about 3.94 times of WO3 (17.78%), while the photodegradation efficiency of WO3 (62.45%) is 2.38 times of urchin-like W18O49 (26.20%). Therefore, urchin-like W18O49 has the best total removal efficiency, which can remove 96.21% of MB (50 ml, 90 mg/L) within 120 min. These studies emphasize the comprehensive effects of WO3 and W18O49 on dye removal from two aspects of adsorption and photocatalysis and provide strategies for the preparation of efficient dye removal materials.



中文翻译:

WO 3和W 18 O 49的吸附性能和光催化活性的合成与比较研究

吸附实验结果表明,具有氧空位的W 18 O 49不仅对MB的吸附速率更快,而且吸附能力大于WO 3。此外,类海胆W 18 O 49(375.94 mg / g)的最大吸附能力约为WO 3(136.25 mg / g)的2.76倍。然而,光催化结果表明WO 3具有比W 18 O 49更好的光催化降解能力。通常,顽童状的W 18 O 49(70.01%)的吸附效率约为WO 3的3.94倍(17.78%),而WO 3(62.45%)的光降解效率是野孩子状W 18 O 49(26.20%)的2.38倍。因此,类似顽童的W 18 O 49具有最佳的总去除效率,可以在120分钟内去除96.21%的MB(50 ml,90 mg / L)。这些研究从吸附和光催化两个方面着重强调了WO 3和W 18 O 49对染料去除的综合作用,并为制备有效的染料去除材料提供了策略。

更新日期:2020-08-28
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