Ionothermal synthesis of crystalline metal phosphites using multifunctional protic ionic liquids,CrystEngComm

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Ionothermal synthesis of crystalline metal phosphites using multifunctional protic ionic liquids
CrystEngComm ( IF 2.6 ) Pub Date : 2020-08-28 , DOI: 10.1039/d0ce01182g
Ting Li _{1,

2,

3,

4} , Yumei Mao _{1,

2,

3,

4} , Yue Qi _{1,

2,

3,

4} , Hongmei Zeng _{1,

2,

3,

4} , Guohong Zou _{1,

2,

3,

4} , Zhien Lin _{1,

2,

3,

4}

Affiliation

Two new crystalline metal phosphites (SCU-9 and SCU-17) were ionothermally prepared using multifunctional protic ionic liquids. SCU-9 has a three-dimensional structure containing both organic templates and organic ligands. SCU-17 is a mixed-valence compound with a layered structure templated by organic cations. This compound is resistant to hydrolysis in boiling water and shows interesting proton-conducting behaviors under 95% relative humidity.

中文翻译：

多功能质子离子液体的离子热合成结晶金属亚磷酸酯

使用多功能质子离子液体通过离子热法制备了两种新的结晶亚磷酸金属盐（SCU-9和SCU-17）。SCU-9具有包含有机模板和有机配体的三维结构。SCU-17是一种混合价化合物，具有以有机阳离子为模板的分层结构。该化合物在沸水中具有抗水解性，并且在95％的相对湿度下显示出有趣的质子传导行为。

更新日期：2020-09-28

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