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3D Graphene Materials: From Understanding to Design and Synthesis Control.
Chemical Reviews ( IF 51.4 ) Pub Date : 2020-08-27 , DOI: 10.1021/acs.chemrev.0c00083 Zhuxing Sun 1 , Siyuan Fang 1 , Yun Hang Hu 1, 2
Chemical Reviews ( IF 51.4 ) Pub Date : 2020-08-27 , DOI: 10.1021/acs.chemrev.0c00083 Zhuxing Sun 1 , Siyuan Fang 1 , Yun Hang Hu 1, 2
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Carbon materials, with their diverse allotropes, have played significant roles in our daily life and the development of material science. Following 0D C60 and 1D carbon nanotube, 2D graphene materials, with their distinctively fascinating properties, have been receiving tremendous attention since 2004. To fulfill the efficient utilization of 2D graphene sheets in applications such as energy storage and conversion, electrochemical catalysis, and environmental remediation, 3D structures constructed by graphene sheets have been attempted over the past decade, giving birth to a new generation of graphene materials called 3D graphene materials. This review starts with the definition, classifications, brief history, and basic synthesis chemistries of 3D graphene materials. Then a critical discussion on the design considerations of 3D graphene materials for diverse applications is provided. Subsequently, after emphasizing the importance of normalized property characterization for the 3D structures, approaches for 3D graphene material synthesis from three major types of carbon sources (GO, hydrocarbons and inorganic carbon compounds) based on GO chemistry, hydrocarbon chemistry, and new alkali-metal chemistry, respectively, are comprehensively reviewed with a focus on their synthesis mechanisms, controllable aspects, and scalability. At last, current challenges and future perspectives for the development of 3D graphene materials are addressed.
中文翻译：
3D石墨烯材料：从理解到设计和综合控制。
碳材料及其同素异形体在我们的日常生活和材料科学的发展中发挥了重要作用。正在关注0D C 60自2004年以来，具有独特引人入胜特性的1D碳纳米管和2D石墨烯材料就受到了广泛关注。为了在能量存储和转换，电化学催化和环境修复，3D结构等应用中有效利用2D石墨烯片材在过去的十年中，人们一直在尝试使用石墨烯片构造石墨烯，从而催生了新一代的石墨烯材料，称为3D石墨烯材料。这篇综述从3D石墨烯材料的定义，分类，简要历史和基本合成化学开始。然后，针对3D石墨烯材料在各种应用中的设计考虑因素进行了重要的讨论。随后，在强调归一化特性表征对于3D结构的重要性之后，分别综述了分别基于GO化学，烃化学和新碱金属化学从三种主要碳源（GO，碳氢化合物和无机碳化合物）合成3D石墨烯材料的方法，可控方面和可伸缩性。最后，解决了3D石墨烯材料开发的当前挑战和未来前景。
更新日期：2020-09-23
中文翻译：
3D石墨烯材料：从理解到设计和综合控制。
碳材料及其同素异形体在我们的日常生活和材料科学的发展中发挥了重要作用。正在关注0D C 60自2004年以来，具有独特引人入胜特性的1D碳纳米管和2D石墨烯材料就受到了广泛关注。为了在能量存储和转换，电化学催化和环境修复，3D结构等应用中有效利用2D石墨烯片材在过去的十年中，人们一直在尝试使用石墨烯片构造石墨烯，从而催生了新一代的石墨烯材料，称为3D石墨烯材料。这篇综述从3D石墨烯材料的定义，分类，简要历史和基本合成化学开始。然后，针对3D石墨烯材料在各种应用中的设计考虑因素进行了重要的讨论。随后，在强调归一化特性表征对于3D结构的重要性之后，分别综述了分别基于GO化学，烃化学和新碱金属化学从三种主要碳源（GO，碳氢化合物和无机碳化合物）合成3D石墨烯材料的方法，可控方面和可伸缩性。最后，解决了3D石墨烯材料开发的当前挑战和未来前景。
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