This study reports the preparation of hierarchical NaP zeolite with the aim of obtaining a non‐phosphate detergent builder as an alternative for environmental remediation from eutrophication phenomenon. Hierarchically structured NaP zeolite was easily synthesized hydrothermally and under different syntheses conditions. Samples were characterized using several standard techniques such as X‐ray diffraction (XRD), scanning electron microscopy (SEM), Fourier transform infrared (FT‐IR) spectroscopy, and N₂ adsorption–desorption analysis. Three powder detergents were prepared by mixing main components such as linear alkylbenzene sulfonate, sodium sulfate, sodium silicate, and sodium carbonate as well as different amounts of as‐synthesized zeolite and sodium tripolyphosphate in the detergent formulation as potential detergency builders. Some different detergency tests as pH value, water insolubility, foam height, moisture content, alcohol insolubility, and surface tension measurement were carried out for all synthetic detergent samples and two commercial ones. The results demonstrated that the high cleaning performance of the powders was obtained as using eco‐friendly zeolite builders in comparison with phosphate‐based commercial and synthetic detergent samples.

中文翻译：

---

方便的水热法合成作为非磷酸盐助洗剂的分级P钠沸石

这项研究报告了分层NaP沸石的制备，目的是获得一种非磷酸盐的洗涤剂助洗剂，以替代富营养化现象对环境的修复。分层结构的NaP沸石很容易在不同的合成条件下水热合成。使用几种标准技术对样品进行表征，例如X射线衍射（XRD），扫描电子显微镜（SEM），傅立叶变换红外（FT-IR）光谱和N ₂吸附-解吸分析。通过混合主要成分（如线性烷基苯磺酸盐，硫酸钠，硅酸钠和碳酸钠）以及洗涤剂配方中不同量的合成沸石和三聚磷酸钠作为潜在的助洗剂，可以制备三种粉末洗涤剂。对所有合成洗涤剂样品和两个商业洗涤剂样品进行了一些不同的去污力测试，例如pH值，水不溶性，泡沫高度，水分含量，醇不溶性和表面张力测量。结果表明，与基于磷酸盐的商业和合成洗涤剂样品相比，使用环保型沸石助洗剂可获得较高的粉末清洁性能。