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Electrochemically assisted photocatalysis for the disinfection of rainwater under solar irradiation
Applied Catalysis B: Environment and Energy ( IF 20.2 ) Pub Date : 2020-08-28 , DOI: 10.1016/j.apcatb.2020.119485
S. McMichael , M. Waso , B. Reyneke , W. Khan , J.A. Byrne , P. Fernandez-Ibanez

In this work a photo electrochemical reactor (PEC) with a compound parabolic collector (CPC) has been designed and tested for the electrochemically assisted photocatalytic (EAP) disinfection of rainwater under real sun conditions in South Africa. The reactor consisted of a Ti mesh coated with aligned titania nanotubes with a carbon counter electrode in a concentric tubular configuration, within a borosilicate glass tube with a CPC. Environmental strains of Escherichia coli and Pseudomonas aeruginosa were used. The viability of the microorganisms was analysed by culture-based and by EMA-qPCR methods. The reactor was tested under real sun during the winter in South Africa with a relatively low UV irradiance (max: 13 Wm-2). Under real sun irradiation, EAP yielded a 5.5-log10 reduction for E. coli and a 5.8-log10 reduction for P. aeruginosa for culture-based analysis. The EAP treatment also showed improved results by EMA-qPCR analysis with a 2.4-log10 reduction in gene copies for E. coli and 3.0-log10 for P. aeruginosa.



中文翻译:

电化学辅助光催化在太阳辐射下消毒雨水

在这项工作中,已经设计并测试了带有复合抛物线收集器(CPC)的光电化学反应器(PEC),用于在南非的真实阳光条件下对雨水进行电化学辅助的光催化(EAP)消毒。该反应器由涂有对准的二氧化钛纳米管的Ti网眼和同心管状配置的碳对电极组成,并在带有CPC的硼硅酸盐玻璃管内。大肠杆菌铜绿假单胞菌的环境菌株被使用。通过基于培养的和通过EMA-qPCR方法分析微生物的生存力。在南非冬季,该反应堆在真实阳光下进行了测试,紫外线辐射相对较低(最大值:13 Wm-2)。在基于阳光的照射下,对于基于培养物的分析,EAP可使大肠杆菌减少5.5-log10 ,铜绿假单胞菌减少5.8-log10 。EAP处理还通过EMA-qPCR分析显示出更好的结果,大肠杆菌的基因拷贝减少了2.4 -log10,铜绿假单胞菌的拷贝减少了3.0-log10

更新日期:2020-09-08
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