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Silver/Palladium Relay Catalyzed Cross‐Coupling of N'‐Acetyl‐8‐quinolinesulfonylhydrazide with Alcohols: An Easy Access to 8‐Quinolinesulfinate Esters
European Journal of Organic Chemistry ( IF 2.8 ) Pub Date : 2020-08-26 , DOI: 10.1002/ejoc.202000911
Anamika Yadav 1, 2 , Mayur D. Ambule 1, 2 , Ruchir Kant 3 , Ajay K. Srivastava 1, 2
Affiliation  

An efficient strategy for the synthesis of unexplored quinoline‐8‐sulfinate esters has been reported through silver and palladium‐catalyzed cross‐coupling of readily available N'‐acetylquinoline‐8‐sulfonohydrazide with a range of 1° and 2° alcohols. Substrate scope, mechanistic studies, and synthetic applications have been explored in detail.
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中文翻译:

银/钯继电器催化N'-乙酰基-8-喹啉磺酰肼与醇的交叉偶联:易于获得8-喹啉亚磺酸酯

通过银和钯催化的现成的N'-乙酰喹啉-8-磺酰肼与一系列1°和2°醇的交叉偶联,已报道了一种有效的合成未开发的喹啉8-亚磺酸酯的策略。已对底物范围,机理研究和合成应用进行了详细探讨。
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更新日期:2020-09-15
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