trans‐Cyclooctenes as Chiral Ligands in Rhodium‐Catalyzed Asymmetric 1,4‐Additions,European Journal of Organic Chemistry

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trans‐Cyclooctenes as Chiral Ligands in Rhodium‐Catalyzed Asymmetric 1,4‐Additions
European Journal of Organic Chemistry ( IF 2.5 ) Pub Date : 2020-08-26 , DOI: 10.1002/ejoc.202000956
Tagui Nagano ₁ , Shunsuke Einaru ₁ , Kenta Shitamichi ₁ , Keisuke Asano ₁ , Seijiro Matsubara ₁

Affiliation

trans‐Cyclooctenes serve as asymmetric ligands during the rhodium‐catalyzed 1,4‐additions of organotin reagents to enones. The potentials of these chiral olefins to provide efficient coordination spheres for asymmetric metal catalysis are demonstrated for the first time. These findings provide chiral frameworks for the design of asymmetric ligands for metal catalysts.