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Pyrene-based metallocycles and metallocages: more than fluorophores
Materials Chemistry Frontiers ( IF 7 ) Pub Date : 2020-08-26 , DOI: 10.1039/d0qm00484g
Xu-Qing Wang 1, 2, 3, 4, 5 , Qing-Hui Ling 1, 2, 3, 4, 5 , Wei Wang 1, 2, 3, 4, 5 , Lin Xu 1, 2, 3, 4, 5
Affiliation  

Attributed to their synthetic accessibility, unique structural and intriguing photophysical features, pyrene moieties have recently been introduced into supramolecular coordination complexes (SCCs) such as metallocycles and metallocages as either functional groups or key panels. The resultant pyrene-based SCCs displayed not only attractive emission properties but also impressive binding abilities towards diverse guests, endowing them with wide applications in sensing, host–guest chemistry, light harvesting etc. In this review, a comprehensive summary of pyrene-based metallocycles and metallocages is presented, and the emphasis will be on the intriguing photophysical features and unique host–guest chemistry that the pyrene moieties bring to the SCCs.

中文翻译:

基金属环和金属位置:超过荧光团

their部分由于其合成的可及性,独特的结构和令人着迷的光物理特性,最近已将pyr部分引入超分子配位配合物(SCC),例如金属环和金属位点作为官能团或键区。所得的pyr基SCC不仅显示出诱人的发射特性,而且还具有与多种客体的惊人结合能力,使其在传感,宿主-客体化学,光收集等方面具有广泛的应用在本篇综述中,of基金属环的概述介绍了金属位点,重点将是the部分带给SCC的有趣的光物理特征和独特的宿主-客体化学。
更新日期:2020-09-16
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