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Tailored polyphenylene sulfite composite with desirable mechanical performance and low dielectric constant by constructing a controllable aramid fiber network
Composites Part B: Engineering ( IF 12.7 ) Pub Date : 2020-08-26 , DOI: 10.1016/j.compositesb.2020.108334
Shiqi Huang , Panlong Lin , Hao Huang , Liang Zhao , Changqing Zhu , Yan Yu , Zongmin Zhu , Kun Nie , Qingquan Tang , Luoxin Wang , Hua Wang

With an increasingly complex working environment and the growing demand in the electrical equipment market, the performance of high-frequency printed circuit boards (PCBs) is generally inadequate, and this problem is due to the failure of either its material or internal architecture. Thus, state-of-the-art PCBs with robust mechanical performance and a low dielectric constant need to be developed. This study proposes a facile technique to fabricate PCBs by assembling aramid fiber (AF) and polyphenylene sulfide (PPS) by combining papermaking and thermocompression lamination. A PPS nonwoven fabric and AFs were first introduced into deionized water and then subjected to intense shearing to form hybrid paper. AF/PPS composite laminates were then fabricated by thermocompression. The as-prepared AF/PPS-30 wt% sample exhibited a flexural strength of 181.4 MPa and a flexural modulus of 13.1 GPa. The sample also achieved a dielectric constant of 3.3 at 15 kHz to 2 MHz, suggesting that the sample exhibited superior dielectric performance and frequency independency as a high-frequency function attributable to the controllable aramid network structure. The dielectric constants of one-dimensional materials reinforced polymer composites were also studied theoretically, and the results presented using the Bruggeman model were consistent with the experimental values. This study provides a feasible strategy for the fabrication of extraordinary PCBs to achieve both desirable mechanical performance and low dielectric constant.



中文翻译:

通过构建可控的芳纶纤维网络,具有理想的机械性能和低介电常数的量身定制的聚亚苯基亚硫酸盐复合材料

随着工作环境的日益复杂和电气设备市场需求的增长,高频印刷电路板(PCB)的性能通常不足,并且此问题是由于其材料或内部架构的故障而引起的。因此,需要开发出具有鲁棒机械性能和低介电常数的最新PCB。这项研究提出了一种通过结合造纸和热压层压来组装芳纶纤维(AF)和聚苯硫醚(PPS)来制造PCB的简便技术。首先将PPS无纺布和AF引入去离子水中,然后进行强力剪切以形成混合纸。然后通过热压法制备AF / PPS复合层压板。所制备的AF / PPS-30 wt%样品的弯曲强度为181。4 MPa,弯曲模量为13.1 GPa。该样品在15 kHz至2 MHz时的介电常数也达到3.3,这表明该样品表现出优异的介电性能和频率独立性,这是归因于可控制的芳族聚酰胺网络结构的高频功能。对一维材料增强的聚合物复合材料的介电常数进行了理论研究,Bruggeman模型的计算结果与实验值吻合。这项研究为制造非凡的PCB提供了可行的策略,以实现理想的机械性能和低介电常数。这表明样品表现出优异的介电性能和频率独立性,这是归因于可控芳族聚酰胺网络结构的高频功能。对一维材料增强的聚合物复合材料的介电常数进行了理论研究,Bruggeman模型的计算结果与实验值吻合。这项研究为制造非凡的PCB提供了可行的策略,以实现理想的机械性能和低介电常数。这表明样品表现出优异的介电性能和频率独立性,这是归因于可控芳族聚酰胺网络结构的高频功能。对一维材料增强的聚合物复合材料的介电常数进行了理论研究,Bruggeman模型的计算结果与实验值吻合。这项研究为制造非凡的PCB提供了可行的策略,以实现理想的机械性能和低介电常数。Bruggeman模型给出的结果与实验值一致。这项研究为制造非凡的PCB提供了可行的策略,以实现理想的机械性能和低介电常数。Bruggeman模型给出的结果与实验值一致。这项研究为制造非凡的PCB提供了可行的策略,以实现理想的机械性能和低介电常数。

更新日期:2020-09-02
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