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Contact Metamorphic and Metasomatic Processes at the Kharaelakh Intrusion, Oktyabrsk Deposit, Norilsk-Talnakh Ore District: Application of LA-ICP-MS Dating of Perovskite, Apatite, Garnet, and Titanite
Economic Geology ( IF 5.5 ) Pub Date : 2020-09-01 , DOI: 10.5382/econgeo.4744
Alexander E. Marfin 1, 2 , Alexei V. Ivanov 1 , Vadim S. Kamenetsky 2, 3 , Adam Abersteiner 3, 4 , Tamara Yu. Yakich 5 , Timur V. Dudkin 1, 6
Affiliation  

The Norilsk-Talnakh ore district in the northwestern Siberian platform contains globally unique reserves of Cu-Ni-sulfides with Pt and, especially, Pd. The Oktyabrsk deposit, which is one of the largest in the district, is spatially and genetically associated with the Kharaelakh mafic-ultramafic intrusion and its exceptionally large metamorphic and metasomatic aureoles. In this study, we employed in situ laser ablation-inductively coupled plasma-mass spectrometry U-Pb isotope dating of apatite, titanite, garnet, and perovskite that cocrystallize with disseminated sulfides within the aureole of metasomatic and contact metamorphic rocks. The calculated isotopic ages for apatite (257.3 ± 4.5 and 248.9 ± 5.1 Ma), titanite (248.6 ± 6.8 and 249.1 ± 2.9 Ma), garnet (260.0 ± 11.0 Ma), and perovskite (247.3 ± 8.2 Ma), though with large uncertainties, indicate that sulfide mineralization within metasomatic and contact-metamorphic rocks is coeval with the emplacement of the Kharaelakh intrusion. These isotopic dates are in complete agreement with the published isotope dilution-thermal ionization mass spectrometry U-Pb zircon ages for the Norilsk intrusions and, at the same time, notably older than available Re-Os isochron ages of sulfides. The latter ages have been long interpreted as evidence for a prolonged duration of magmatic ore-forming processes; however, our data narrow their life span. Trace elements in titanite and garnet allow distinguishing late- and postmagmatic grains, which show indistinguishable U-Pb isotope ages.

中文翻译:

诺里尔斯克-塔尔纳赫矿石区的哈拉拉克侵入岩,俄克拉布斯克矿床的接触变质和变质过程:钙钛矿,磷灰石,石榴石和钛矿的LA-ICP-MS测年

西伯利亚平台西北部的诺里尔斯克-塔尔纳克(Norilsk-Talnakh)矿区拥有全球独一无二的含Pt(尤其是Pd)的Cu-Ni-硫化物储量。Oktyabrsk矿床是该地区最大的矿床之一,在空间和遗传上与Kharaelakh黑镁质-超镁铁质侵入岩及其异常大的变质和变质金闪石有关。在这项研究中,我们采用原位激光烧蚀-电感耦合等离子体质谱法对磷灰石,钛矿,石榴石和钙钛矿进行U-Pb同位素测年,它们与变质岩和接触变质岩的金矿中的弥散硫化物共结晶。磷灰石(257.3±4.5和248.9±5.1 Ma),钛矿(248.6±6.8和249.1±2.9 Ma),石榴石(260.0±11.0 Ma)和钙钛矿(247.3±8.2 Ma)的计算同位素年龄,尽管存在很大的不确定性,指出,变质岩和接触变质岩中的硫化物矿化与Kharaelakh侵入岩的侵入同时期。这些同位素数据与已发表的同位素稀释-热电离质谱用于Norilsk侵入的U-Pb锆石年龄完全吻合,并且同时明显比可用的Re-Os硫化物等时年龄大。长期以来,后一个年龄被认为是岩浆成矿过程持续时间延长的证据。但是,我们的数据缩短了它们的寿命。钛铁矿和石榴石中的痕量元素可以区分晚岩浆期和后岩浆期,它们显示出不可区分的U-Pb同位素年龄。这些同位素数据与已发表的同位素稀释-热电离质谱用于Norilsk侵入的U-Pb锆石年龄完全吻合,并且同时明显比可用的Re-Os硫化物等时年龄大。长期以来,后一个年龄被认为是岩浆成矿过程持续时间延长的证据。但是,我们的数据缩短了它们的寿命。钛铁矿和石榴石中的痕量元素可以区分晚岩浆期和后岩浆期,它们显示出不可区分的U-Pb同位素年龄。这些同位素数据与已发表的同位素稀释-热电离质谱用于Norilsk侵入的U-Pb锆石年龄完全吻合,并且同时明显比可用的Re-Os硫化物等时年龄大。长期以来,后一个年龄被认为是岩浆成矿过程持续时间延长的证据。但是,我们的数据缩短了它们的寿命。钛铁矿和石榴石中的痕量元素可以区分晚岩浆期和后岩浆期,它们显示出不可区分的U-Pb同位素年龄。长期以来,后一个年龄被认为是岩浆成矿过程持续时间延长的证据。但是,我们的数据缩短了它们的寿命。钛铁矿和石榴石中的痕量元素可以区分晚岩浆期和后岩浆期,它们显示出不可区分的U-Pb同位素年龄。长期以来,后一个年龄被认为是岩浆成矿过程持续时间延长的证据。但是,我们的数据缩短了它们的寿命。钛铁矿和石榴石中的痕量元素可以区分晚岩浆期和后岩浆期,它们显示出不可区分的U-Pb同位素年龄。
更新日期:2020-08-25
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