Fast and Chemoselective Addition of Highly Polarized Lithium Phosphides Generated in Deep Eutectic Solvents to Aldehydes and Epoxides,ChemSusChem

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Fast and Chemoselective Addition of Highly Polarized Lithium Phosphides Generated in Deep Eutectic Solvents to Aldehydes and Epoxides
ChemSusChem ( IF 7.5 ) Pub Date : 2020-08-25 , DOI: 10.1002/cssc.202001869
Luciana Cicco ₁ , Alba Fombona‐Pascual _{2,

3} , Alba Sánchez‐Condado ₂ , Gabino A. Carriedo ₂ , Filippo M. Perna ₁ , Vito Capriati ₁ , Alejandro Presa Soto ₂ , Joaquín García‐Álvarez ₃

Affiliation

The Cover Feature shows an unprecedented generation of highly polarized lithium phosphides (LiPR₂) through direct selective deprotonation of secondary phosphines (HPR₂) in the biodegradable choline chloride/glycerol eutectic mixture, at ambient temperature and under aerobic conditions, and their chemoselective addition to aldehydes or epoxides. More information can be found in the Full Paper by L. Cicco et al.

中文翻译：

在深共溶剂中生成的高极化磷酸锂快速和化学选择性加成到醛和环氧化物上

Cover Feature展示了在环境温度和好氧条件下，可生物降解的氯化胆碱/甘油共晶混合物中仲膦的直接选择性去质子化（HPR ₂），空前产生了高度极化的磷化锂（LiPR ₂），以及它们的化学选择性添加醛或环氧化物。可以在L. Cicco等人的论文全文中找到更多信息。

更新日期：2020-09-24

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