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Rigidly Fused Spiro-Conjugated π-Systems.
ChemPlusChem ( IF 3.0 ) Pub Date : 2020-08-24 , DOI: 10.1002/cplu.202000467
Shihui Liu 1 , Debin Xia 1 , Martin Baumgarten 2
Affiliation  

Spiro‐fused π‐systems have gained considerable attention for their application as semiconductors in molecular electronics. Here, a synopsis regarding recent breakthroughs in ladderized spirobifluorenes and indeno‐spirobifluorenes, along with further spiro‐condensed heteroatomic hydrocarbons with donor‐acceptor moieties, is provided. Additionally, an extended range of rigid spirobifluorene polymers and specific doubly linked spiro‐systems with partial chiral character is discussed. The diverse applications of the aforementioned structures are thoroughly evaluated.

中文翻译:

刚性融合的螺旋共轭π系统。

螺旋融合π系统在分子电子学中作为半导体的应用受到了广泛的关注。这里提供了有关梯形螺双芴和茚并螺双芴以及具有供体-受体部分的进一步螺缩杂原子烃的近期突破的概述。此外,还讨论了扩展的刚性螺二芴聚合物和具有部分手性特征的特定双链螺体系。全面评估了上述结构的各种应用。
更新日期:2020-08-24
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