With the emergence of non-conventional energy resources and development of energy storage devices, serious efforts on lithium (Li) based rechargeable solid electrolyte batteries (Li- SEBs) are attaining momentum due to their potential as a safe candidate to replace state-of-the-art conventionally existing flammable organic liquid electrolyte-based Li-ion batteries (LIBs). However, Li-ion conduction in solid electrolytes (SEs) has been one of the major bottlenecks in large scale commercialization of next-generation Li-SEBs. Here, in this review, various challenges in the realization of high-performance Li-SEBs are discussed and recent strategies employed for the development of efficient SEs are reviewed. In addition, special focus is laid on the ionic conductivity enhancement techniques for inorganic (including ceramics, glasses, and glass-ceramics) and polymersbased SEs. The development of novel fabrication routes with controlled parameters and highperformance temperature optimized SEs with stable electrolyte-electrode interfaces are proposed to realize highly efficient Li-SEBs.

随着非常规能源的出现和储能设备的发展，基于锂（Li）的可充电固体电解质电池（Li SEBs）正认真努力，因为它们有潜力替代安全状态，因此势在必行。现有技术中现有的基于易燃有机液体电解质的锂离子电池（LIB）。但是，固体电解质（SEs）中的锂离子传导一直是下一代Li-SEB大规模商业化的主要瓶颈之一。在这里，在这篇综述中，讨论了高性能Li-SEB实现中的各种挑战，并对用于开发高效SE的最新策略进行了综述。此外，还特别关注无机物（包括陶瓷，玻璃，和玻璃陶瓷）和基于聚合物的SE。提出了具有受控参数和具有稳定的电解质-电极界面的高性能温度优化SE的新颖制造路线的开发，以实现高效的Li-SEB。