Inorganic and Nano-Metal Chemistry ( IF 1.4 ) Pub Date : 2020-08-20 , DOI: 10.1080/24701556.2020.1808993 Muhammad Imran Din 1 , Rimsha Rizwan 1 , Zaib Hussain 1 , Rida Khalid 1
Abstract
Copper and copper oxide nanoparticles (Co/CoO NPs) were synthesized by a green approach using Syzygium cumini leaf extract. The formation of synthesized Co/CoO NPs was monitored by using UV–Visible spectroscopy which shows surface plasmon resonance (SPR) at 380 nm. The parameters affecting the particle size or yield of Co/CoO NPs including pH, temperature, reaction time, and concentration of salt also has been studied. The performance or efficiency of catalysts has been investigated by the degradation of 4-nitrophenol (4-NP) and methylene blue (MB) in the presence of sodium borohydride. The kinetic studies displayed that Co/CoO NPs obeyed pseudo-first-order for catalysis of selected contaminants.
中文翻译:
利用孜然叶催化合成单分散Co / CoO纳米粒子
摘要
使用Syzygium cumini叶提取物通过绿色方法合成了铜和氧化铜纳米颗粒(Co / CoO NPs)。合成的Co / CoO NP的形成通过使用紫外可见光谱法进行监测,该光谱显示了380 nm的表面等离振子共振(SPR)。还研究了影响Co / CoO NP粒径或收率的参数,包括pH,温度,反应时间和盐浓度。已经通过在硼氢化钠存在下降解4-硝基苯酚(4-NP)和亚甲基蓝(MB)来研究催化剂的性能或效率。动力学研究表明,Co / CoO NPs在选择的污染物催化过程中服从拟一阶反应。