Photochemical O−H Functionalization Reactions of Cyclic Diazoamides,Advanced Synthesis & Catalysis

当前位置： X-MOL 学术 › Adv. Synth. Catal. › 论文详情

Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)

Photochemical O−H Functionalization Reactions of Cyclic Diazoamides
Advanced Synthesis & Catalysis ( IF 4.4 ) Pub Date : 2020-08-20 , DOI: 10.1002/adsc.202000818
Claire Empel ₁ , Dennis Verspeek ₁ , Sripati Jana ₁ , Rene M. Koenigs ₁

Affiliation

Herein, we describe the photochemical O−H functionalization reaction of acidic alcohols with cyclic diazoamides. We studied the O−H functionalization reaction of different fluorinated and non‐fluorinated alcohols to give the corresponding ether products in high yields (43 examples, up to 97% yield). Furthermore, we performed studies to evaluate a photoexcited proton transfer reaction pathway in comparison to classic carbene transfer reactions.

中文翻译：