Reductive Carbon–Carbon Bond Forming Reactions with Carbonyls Mediated by Rh–H Complexes,European Journal of Organic Chemistry

当前位置： X-MOL 学术 › Eur. J. Org. Chem. › 论文详情

Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)

Reductive Carbon–Carbon Bond Forming Reactions with Carbonyls Mediated by Rh–H Complexes
European Journal of Organic Chemistry ( IF 2.5 ) Pub Date : 2020-08-20 , DOI: 10.1002/ejoc.202001041
Kazuyuki Sato ₁ , Motoyuki Isoda ₂ , Atsushi Tarui ₁ , Masaaki Omote ₁

Affiliation

Reductive carbon–carbon bond forming reaction of α,β‐unsaturated carbonyls is a preferable method to insert electrophiles at α‐position of carbonyl group, regioselectively. In this minireview, we summarized our works related to Rh‐catalyzed reductive aldol reaction, reductive Mannich reaction, and reductive α‐acylation together with recent aspects of metal catalyzed reductive C–C bond formations.

中文翻译：

Rh-H配合物介导的羰基还原性碳-碳键形成反应

α，β-不饱和羰基的还原碳-碳键形成反应是在区域选择性地将亲电试剂插入羰基的α-位置的一种优选方法。在这份小型回顾中，我们总结了与Rh催化的还原性羟醛反应，Mannich还原反应和α-酰化还原反应有关的工作，以及金属催化的CC还原键形成的最新进展。

更新日期：2020-08-20

点击分享查看原文

点击收藏

公开下载

阅读更多本刊最新论文本刊介绍/投稿指南11