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Magnetic Nanoparticle Supported Ionic Liquid Phase Catalyst for Oxidation of Alcohols
Australian Journal of Chemistry ( IF 1.0 ) Pub Date : 2020-06-25 , DOI: 10.1071/ch19627
Altafhusen Naikwade , Megha Jagadale , Dolly Kale , Gajanan Rashinkar

A new magnetic nanoparticle supported ionic liquid phase (SILP) catalyst containing perruthenate anions was prepared by a multistep procedure. The various analytical techniques such as FT-IR spectroscopy, X-ray photoelectron spectroscopy, transmission electron microscopy, thermogravimetric analysis, energy dispersive X-ray analysis, and vibrating sample magnetometer analysis ascertained the successful formation of catalyst. The performance of a magnetically retrievable SILP catalyst was evaluated in the selective oxidation of alcohols. The split test and leaching studies of the SILP catalyst confirmed its heterogeneous nature. In addition, the reusability potential of SILP catalyst was also investigated which revealed its robust activity up to six consecutive cycles.



中文翻译:

磁性纳米粒子负载的离子液体催化氧化醇

通过多步骤程序制备了一种新的磁性纳米粒子负载的离子液相(SILP)催化剂,该催化剂含有高铝酸盐阴离子。FT-IR光谱,X射线光电子能谱,透射电子显微镜,热重分析,能量色散X射线分析和振动样品磁强计分析等各种分析技术确定了催化剂的成功形成。在醇的选择性氧化中,评估了可磁性回收的SILP催化剂的性能。SILP催化剂的分裂试验和浸出研究证实了其非均相性质。此外,还研究了SILP催化剂的可重复使用潜力,揭示了其在六个连续循环中的强大活性。

更新日期:2020-08-20
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