Asymmetric Synthesis of 1-Tetralones Bearing A Remote Quaternary Stereocenter through Rh-Catalyzed C−C Activation of Cyclopentanones,Bulletin of the Chemical Society of Japan

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Asymmetric Synthesis of 1-Tetralones Bearing A Remote Quaternary Stereocenter through Rh-Catalyzed C−C Activation of Cyclopentanones
Bulletin of the Chemical Society of Japan ( IF 3.3 ) Pub Date : 2020-10-15 , DOI: 10.1246/bcsj.20200147
Shusuke Ochi ₁ , Ying Xia ₁ , Guangbin Dong ₁

Affiliation

Herein, we describe the preparation of 1-tetralones bearing a remote quaternary stereocenter in a highly enantioselective manner. A sequence of Pd-catalyzed asymmetric 1,4-addition and Rh-catalyzed...

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