Mechanism Change of (+)-Nonlinear Effect in a Phase Separation System in a CuII-catalyzed Asymmetric Friedel-Crafts Reaction Using a C2-Chiral Dioxolane-containing-bisamidine Ligand, Naph-diPIM-dioxo-iPr,Bulletin of the Chemical Society of Japan

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Mechanism Change of (+)-Nonlinear Effect in a Phase Separation System in a CuII-catalyzed Asymmetric Friedel-Crafts Reaction Using a C2-Chiral Dioxolane-containing-bisamidine Ligand, Naph-diPIM-dioxo-iPr
Bulletin of the Chemical Society of Japan ( IF 3.3 ) Pub Date : 2020-11-15 , DOI: 10.1246/bcsj.20200172
Thien Phuc Le ₁ , Shinji Tanaka ₂ , Masahiro Yoshimura ₃ , Masato Kitamura ₁

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A CuII complex of bisamidine ligand LS, chirally modified naphtho[1,2-b:7,8-b′]dipyrroloimidazole (Naph-diPIM), catalyzes the enantioselective Friedel-Crafts (FC) reaction of indole (1a) with ethyl...

中文翻译：

使用含 C2-手性二氧戊环的双脒配体 Naph-diPIM-dioxo-iPr 的 CuII 催化的不对称弗瑞德-克来福特反应中 (+)-非线性效应的机制变化

双脒配体 LS 的 CuII 复合物，手性改性的萘并 [1,2-b:7,8-b'] 二吡咯并咪唑 (Naph-diPIM)，催化吲哚 (1a) 与乙基的对映选择性弗里德尔-克拉夫茨 (FC) 反应。 ..

更新日期：2020-11-15

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