Published data on the coordination compounds of group 5 metals with diimine type ligands are surveyed. Methods of synthesis, structural types, reactivity and properties of these compounds are summarized and systematized. Particular attention is paid to the redox, magnetic and catalytic properties and to biological activities of these complexes, which is important for understanding the areas of their potential application.

The bibliography includes 177 references.

中文翻译：

---

第 5 族金属与二亚胺配体的单核和双核配合物：合成、反应性和应用前景

调查了关于第 5 族金属与二亚胺型配体的配位化合物的已发表数据。对这些化合物的合成方法、结构类型、反应性和性质进行了总结和系统化。特别关注这些配合物的氧化还原、磁性和催化特性以及生物活性，这对于了解它们的潜在应用领域很重要。

参考书目包括 177 篇参考文献。