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NH4I-catalyzed C–S bond formation via an oxidation relay strategy: Efficient access to dithioether decorated indolizines
Tetrahedron Letters ( IF 1.5 ) Pub Date : 2020-08-20 , DOI: 10.1016/j.tetlet.2020.152368 Yu Zhu , Liechao Yang , Liyun Fang , Xiaofan Du , Keda Chen , Chuanming Yu , Xinpeng Jiang
中文翻译:
NH 4 I通过氧化中继策略催化C–S键形成:有效获得二硫醚修饰的吲哚嗪
更新日期:2020-09-18
Tetrahedron Letters ( IF 1.5 ) Pub Date : 2020-08-20 , DOI: 10.1016/j.tetlet.2020.152368 Yu Zhu , Liechao Yang , Liyun Fang , Xiaofan Du , Keda Chen , Chuanming Yu , Xinpeng Jiang
An efficient NH4I-catalyzed C–H/S–H cross-coupling reaction of indolizines with thiols is reported. Compared to previous methods, this environmentally friendly oxidation relay strategy uses O2 as an oxidant to afford dithioether decorated indolizines in up to 98% yield. Promising results have been obtained, indicating the high applicability and atom economy of this method.
中文翻译:
NH 4 I通过氧化中继策略催化C–S键形成:有效获得二硫醚修饰的吲哚嗪
据报道,吲哚嗪类与硫醇的高效NH 4 I催化C–H / S–H交叉偶联反应。与以前的方法相比,这种环境友好的氧化中继策略使用O 2作为氧化剂,以高达98%的产率提供二硫醚修饰的吲哚嗪。获得了令人鼓舞的结果,表明该方法的高度适用性和原子经济性。