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Water-soluble fluorescent chemosensor based on Schiff base derivative terminated PEG for highly efficient detection of Al3+ in pure aqueous media
Tetrahedron Letters ( IF 1.5 ) Pub Date : 2020-08-20 , DOI: 10.1016/j.tetlet.2020.152335
Yuhang Xu , Leixuan Li , Liping Bai , Shuhui Tian , Litian Zhang , Xiuyu Huang , Yan Zhu , Farong Tao , Liping Wang , Guang Li

Schiff base derivative terminated PEG (PEGESB) was synthesized and applied as fluorescent chemosensor in pure aqueous media. PEGESB exhibited excellent selectivity and anti-interference ability for Al3+ with naked eye fluorescence color change from colorless to bright cyan. The detection limit of PEGESB for Al3+ was determined to be as low as 2.93 × 10−9 M. PEGESB was stable and could effectively detect Al3+ over a wide pH range from 5 to 10. PEGESB was proved to be a reversible fluorescent chemosensor upon alternate addition of Al3+ and EDTA to PEGESB aqueous solution. The fluorescence response of PEGESB solution to Al3+ and EDTA was applied to build an INHIBIT logic gate. In addition, test papers coated with PEGESB were facilely prepared for on-site sensing of Al3+ in real water samples.



中文翻译:

基于席夫碱衍生物终止的PEG的水溶性荧光化学传感器,用于高效检测纯水介质中的Al 3+

合成了席夫碱衍生物终止的PEG(PEGESB),并在纯水介质中用作荧光化学传感器。PEGESB对Al 3+具有优异的选择性和抗干扰能力,并且肉眼荧光的颜色从无色变为亮青色。PEGESB的用于铝的检测限3+测定为低至2.93×10 -9 M. PEGESB是稳定的并能有效地检测出的Al 3+在宽的pH范围是5〜10 PEGESB被证明是一个可逆向PEGESB水溶液中交替添加Al 3+和EDTA的荧光化学传感器。PEGESB溶液对Al 3+的荧光响应EDTA被用于构建INHIBIT逻辑门。另外,已经准备好涂有PEGESB的试纸,用于现场感测真实水样中的Al 3+

更新日期:2020-09-18
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