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Trihaloisocyanuric Acids: Useful Reagents for Conversion of Benzaldehydes into Benzylidene Dihalides under Appel Conditions
Letters in Organic Chemistry ( IF 0.7 ) Pub Date : 2020-07-31 , DOI: 10.2174/1570178617666200121110618 Haryadylla da C. Sindra 1 , Carlos Vinícius P. dos Santos 1 , Marcio C.S. de Mattos 1
中文翻译:
三卤代异氰尿酸:有用的试剂,可在阿普尔条件下将苯甲醛转化为亚苄基二卤化物
更新日期:2020-07-31
Letters in Organic Chemistry ( IF 0.7 ) Pub Date : 2020-07-31 , DOI: 10.2174/1570178617666200121110618 Haryadylla da C. Sindra 1 , Carlos Vinícius P. dos Santos 1 , Marcio C.S. de Mattos 1
Affiliation
The reaction of substituted benzaldehydes with tribromoisocyanuric acid and triphenylphosphine led to the corresponding benzylidene dibromides (95-99%). Similar reaction using trichloroisocyanuric acid produced benzylidene dichlorides (38-96%).
中文翻译:
三卤代异氰尿酸:有用的试剂,可在阿普尔条件下将苯甲醛转化为亚苄基二卤化物
取代的苯甲醛与三溴异氰尿酸和三苯基膦的反应生成相应的亚苄基二溴化物(95-99%)。使用三氯异氰尿酸的类似反应产生了亚苄基二氯化物(38-96%)。