Abstract

Hydrosilylation of multiple carbon–carbon bonds is a well-known process for the construction of organosilicon compounds. Nowadays, precious metal catalysts, especially platinum complexes, still occupy dominant positions in such processes. However, one important member of the precious metal family, iridium, is less used in this field. As early research mainly focused on developing stable and effective iridium catalysts, recent advances have disclosed the specific efficiency of simple iridium catalytic systems in the synthesis of functional organo­silicon compounds. This short review summarizes the utilization of iridium complexes for the hydrosilylation of alkenes and alkynes, with an emphasis on the recent advances published in the last decade.

1 Introduction

2 Iridium-Catalyzed Hydrosilylation of Alkenes

3 Iridium-Catalyzed Hydrosilylation of Alkynes

4 Conclusions and Perspectives

Key words

iridium

catalysis

hydrosilylation

alkenes

alkynes

中文翻译：

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铱催化烯烃和炔烃的氢化硅烷化研究进展

摘要

多个碳-碳键的氢化硅烷化是构建有机硅化合物的众所周知的过程。如今，贵金属催化剂，尤其是铂络合物在此类工艺中仍占据主导地位。但是，该领域很少使用贵金属家族的重要成员铱。由于早期研究主要集中在开发稳定和有效的铱催化剂上，所以最近的进展已经公开了简单铱催化体系在合成功能有机硅化合物中的特定效率。这篇简短的综述总结了铱配合物在烯烃和炔烃的氢化硅烷化中的应用，并着重介绍了过去十年中发表的最新进展。

1引言

2铱催化烯烃的氢化硅烷化

3铱催化的炔烃氢化硅烷化

4结论与观点

关键词

铱

催化

氢化硅烷化

烯烃

炔烃