当前位置：
X-MOL 学术
›
J. Chin. Chem. Soc.
›
论文详情
Our official English website, www.x-mol.net, welcomes your
feedback! (Note: you will need to create a separate account there.)
Cyclometalated iridium(III) complexes containing 2‐phenyl‐2H‐indazole ligand: Synthesis, photophysical studies, and DFT calculations
Journal of the Chinese Chemical Society ( IF 1.6 ) Pub Date : 2020-08-18 , DOI: 10.1002/jccs.202000271 Shao‐Bin Dou 1 , Xing‐Liang Jia 1 , Zhi‐Jun Liu 1 , Ya‐Qi Meng 1 , Zheng‐Rong Mo 2 , Gao‐Nan Li 1 , Zhi‐Gang Niu 2
Journal of the Chinese Chemical Society ( IF 1.6 ) Pub Date : 2020-08-18 , DOI: 10.1002/jccs.202000271 Shao‐Bin Dou 1 , Xing‐Liang Jia 1 , Zhi‐Jun Liu 1 , Ya‐Qi Meng 1 , Zheng‐Rong Mo 2 , Gao‐Nan Li 1 , Zhi‐Gang Niu 2
Affiliation
|
Heteroleptic cyclometalated iridium(III) complexes (Ir1–Ir5) featuring piz‐based ligands and acetylacetone ancillary ligand are synthesized and characterized. Their photophysical and electrochemical properties were studied, and DFT calculations were used to further support the experiment results. All the complexes emit yellow color with quantum yields of 12.2–56.5% in dichloromethane solution at room temperature, and the emission originates from a hybrid 3MLCT/3ILCT/3LLCT excited state.
中文翻译：
含有2-苯基-2H-吲唑配体的环金属化铱（III）配合物：合成，光物理研究和DFT计算
杂环金属化铱（III）配合物（IR1 - IR5设有基于PIZ配体和乙酰丙酮辅助配体的合成和表征）。研究了它们的光物理和电化学性质，并使用DFT计算来进一步支持实验结果。在室温下，所有络合物在二氯甲烷溶液中发出黄色光，量子产率为12.2–56.5％，并且发射源自杂化3 MLCT / 3 ILCT / 3 LLCT激发态。
更新日期：2020-09-24
中文翻译：
含有2-苯基-2H-吲唑配体的环金属化铱（III）配合物：合成，光物理研究和DFT计算
杂环金属化铱（III）配合物（IR1 - IR5设有基于PIZ配体和乙酰丙酮辅助配体的合成和表征）。研究了它们的光物理和电化学性质，并使用DFT计算来进一步支持实验结果。在室温下，所有络合物在二氯甲烷溶液中发出黄色光，量子产率为12.2–56.5％，并且发射源自杂化3 MLCT / 3 ILCT / 3 LLCT激发态。
京公网安备 11010802027423号