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A convenient P- source.
Nature Chemistry ( IF 19.2 ) Pub Date : 2020-08-17 , DOI: 10.1038/s41557-020-0534-0
David Scheschkewitz 1
Affiliation  

White phosphorus is a prominent source of P atoms but has remained difficult to activate without using transition metals. Now, a bidentate ligand based on silicon(ii) donors has successfully stabilized a P2 moiety, and the resulting complex acts as a transfer reagent for P– anions.

中文翻译:

方便的P源。

白磷是P原子的主要来源,但在不使用过渡金属的情况下仍然难以活化。现在,基于硅(ii)供体的双齿配体已成功稳定了P2部分,并且所形成的络合物充当了P–阴离子的转移试剂。
更新日期:2020-10-19
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