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Fe3O4@nSiO2@mSiO2/DBU: A Novel and Effective Basic Magnetic Nanocatalyst in the Multicomponent One Pot Synthesis of Polyhydroacridines and Polyhydroquinolines
Polycyclic Aromatic Compounds ( IF 2.4 ) Pub Date : 2020-08-17
Mehran Honari, Ali Reza Kiasat, Haleh Sanaeishoar, Mohammad Kazem Mohammadi

In this research work, magnetic nanoparticles (NPs) of Fe3O4@nSiO2@mSiO2/DBU were designed as a novel effective heterogeneous catalyst for the production of polyhydroacridines and polyhydroquinolines. For characterizing the NPs, the Fourier transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM), transmission electron microscope (TEM), vibrating sample magnetometry (VSM), thermogravimetric analysis (TGA), X-ray diffraction (XRD), and N2 adsorption–desorption measurement (BET isotherm) techniques were used. Some advantages of this magnetic nanoparticle include: use of commercially available materials to make catalysts, appropriate and simple operation, excellent yields, appropriate catalytic activity, simple work-up, and recycle and reuse the catalyst up to seven times without considerable change in its catalytic activity.



中文翻译:

Fe3O4 @ nSiO2 @ mSiO2 / DBU:一种新型有效的碱性磁性纳米催化剂,用于多组分一锅法合成聚氢ac啶和聚氢喹啉

在这项研究工作中,Fe 3 O 4 @nSiO 2 @mSiO 2 / DBU的磁性纳米颗粒(NPs)被设计为新型有效的非均相催化剂,用于生产聚氢ac啶和聚氢喹啉。为了表征NP,使用傅立叶变换红外光谱(FT-IR),扫描电子显微镜(SEM),透射电子显微镜(TEM),振动样品磁力法(VSM),热重分析(TGA),X射线衍射(XRD)和N 2使用了吸附-解吸测量(BET等温线)技术。这种磁性纳米颗粒的一些优点包括:使用可商购的材料制造催化剂,适当而简单的操作,优异的收率,适当的催化活性,简单的后处理,以及多达7次的循环和再利用催化剂,而其催化性能没有明显变化活动。

更新日期:2020-08-17
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