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An Overview of the Flame Retardants for Poly(vinyl chloride): Recent States and Perspective†
Chinese Journal of Chemistry ( IF 5.5 ) Pub Date : 2020-08-17 , DOI: 10.1002/cjoc.202000375 Ye‐Tang Pan 1 , Yongshuai Yuan 1 , De‐Yi Wang 2 , Rongjie Yang 1
As a versatile star product, poly(vinyl chloride) (PVC) has kept active in our daily life all through since it was invented. However, the severe fire hazard and heavy smoke produced during combustion, particularly the extensively used flexible PVC products, have been puzzling manufacturers and researchers for ages. Over the last decade, multifarious flame retardants and smoke suppressants were developed for PVC materials. In this review, combined literature with the results based on the research from our group, recent emerged flame retardants and smoke suppressants for PVC are introduced. Meanwhile, the flame retardant mechanisms and experimental analysis results are described to understand the relationship between characters of flame retardants (including chemical compositions, structures or morphologies) and fire performance of the composites. The potential substitutes for traditional harmful flame retardant antimony trioxide are discussed aiming to the emphasis on increasing prominent environmental concerns. In particular, one section is dedicated to new approaches for the preparation of novel environmentally friendly and high‐efficiency flame retardants. It is hoped that this review will not only summarize the new emerged flame retardants and smoke suppressants for PVC, but also provide the new trend to prompt sequent exploration in both academic research and industrial application.
中文翻译：
聚氯乙烯阻燃剂概述：最新状态和观点†
自从发明以来，作为一种多功能明星产品，聚氯乙烯（PVC）一直活跃在我们的日常生活中。但是，燃烧期间产生的严重火灾隐患和浓烟，尤其是广泛使用的柔性PVC产品，已经使制造商和研究人员困惑了很长时间。在过去的十年中，为PVC材料开发了多种阻燃剂和抑烟剂。在这篇综述中，结合文献和基于我们小组研究的结果，介绍了最近出现的用于PVC的阻燃剂和抑烟剂。同时，描述了阻燃剂的机理和实验分析结果，以了解阻燃剂的特性（包括化学成分，结构或形态）与复合材料的防火性能之间的关系。讨论了传统有害阻燃三氧化二锑的潜在替代品，旨在强调日益突出的环境问题。特别是，一节专门介绍了用于制备新型环保和高效阻燃剂的新方法。希望这篇综述不仅能总结出新兴的PVC阻燃剂和抑烟剂，而且能提供新的趋势，以促进随后在学术研究和工业应用中的探索。其中一节专门介绍了用于制备新型环保高效阻燃剂的新方法。希望这篇综述不仅能总结出新兴的PVC阻燃剂和抑烟剂，而且能提供新的趋势，以促进随后在学术研究和工业应用中的探索。其中一部分专门介绍了用于制备新型环保高效阻燃剂的新方法。希望这篇综述不仅能总结出新兴的PVC阻燃剂和抑烟剂，而且能提供新的趋势，以促进随后在学术研究和工业应用中的探索。
更新日期：2020-08-17
Chinese Journal of Chemistry ( IF 5.5 ) Pub Date : 2020-08-17 , DOI: 10.1002/cjoc.202000375 Ye‐Tang Pan 1 , Yongshuai Yuan 1 , De‐Yi Wang 2 , Rongjie Yang 1
Affiliation
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As a versatile star product, poly(vinyl chloride) (PVC) has kept active in our daily life all through since it was invented. However, the severe fire hazard and heavy smoke produced during combustion, particularly the extensively used flexible PVC products, have been puzzling manufacturers and researchers for ages. Over the last decade, multifarious flame retardants and smoke suppressants were developed for PVC materials. In this review, combined literature with the results based on the research from our group, recent emerged flame retardants and smoke suppressants for PVC are introduced. Meanwhile, the flame retardant mechanisms and experimental analysis results are described to understand the relationship between characters of flame retardants (including chemical compositions, structures or morphologies) and fire performance of the composites. The potential substitutes for traditional harmful flame retardant antimony trioxide are discussed aiming to the emphasis on increasing prominent environmental concerns. In particular, one section is dedicated to new approaches for the preparation of novel environmentally friendly and high‐efficiency flame retardants. It is hoped that this review will not only summarize the new emerged flame retardants and smoke suppressants for PVC, but also provide the new trend to prompt sequent exploration in both academic research and industrial application.
中文翻译：
聚氯乙烯阻燃剂概述：最新状态和观点†
自从发明以来，作为一种多功能明星产品，聚氯乙烯（PVC）一直活跃在我们的日常生活中。但是，燃烧期间产生的严重火灾隐患和浓烟，尤其是广泛使用的柔性PVC产品，已经使制造商和研究人员困惑了很长时间。在过去的十年中，为PVC材料开发了多种阻燃剂和抑烟剂。在这篇综述中，结合文献和基于我们小组研究的结果，介绍了最近出现的用于PVC的阻燃剂和抑烟剂。同时，描述了阻燃剂的机理和实验分析结果，以了解阻燃剂的特性（包括化学成分，结构或形态）与复合材料的防火性能之间的关系。讨论了传统有害阻燃三氧化二锑的潜在替代品，旨在强调日益突出的环境问题。特别是，一节专门介绍了用于制备新型环保和高效阻燃剂的新方法。希望这篇综述不仅能总结出新兴的PVC阻燃剂和抑烟剂，而且能提供新的趋势，以促进随后在学术研究和工业应用中的探索。其中一节专门介绍了用于制备新型环保高效阻燃剂的新方法。希望这篇综述不仅能总结出新兴的PVC阻燃剂和抑烟剂，而且能提供新的趋势，以促进随后在学术研究和工业应用中的探索。其中一部分专门介绍了用于制备新型环保高效阻燃剂的新方法。希望这篇综述不仅能总结出新兴的PVC阻燃剂和抑烟剂，而且能提供新的趋势，以促进随后在学术研究和工业应用中的探索。
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