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Synthesis, structure and magnetic properties of Sm1.2Ho0.8Fe17Нx (x = 0; 4.4)
Journal of Rare Earths ( IF 4.9 ) Pub Date : 2020-08-16 , DOI: 10.1016/j.jre.2020.08.010
S.V. Veselova , M.A. Paukov , I.S. Tereshina , V.N. Verbetsky , K.V. Zakharov , D.I. Gorbunov , A.N. Vasil’ev

Intermetallic compounds based on rare-earth metals and iron are by far the most promising materials for permanent magnets. In this work, the multicomponent compound Sm1.2Ho0.8Fe17 was prepared by induction melting. The hydride Sm1.2Ho0.8Fe17H4.4 with a high hydrogen content was obtained by direct hydrogenation of the intermetallic compound. The rhombohedral Th2Zn17-type of structure (space group R3¯m) is inherent to parent compound and hydride as well. The effect of hydrogenation on the magnetic properties of Sm1.2Ho0.8Fe17 was investigated. Curie temperature of the hydride Sm1.2Ho0.8-Fe17H4.4 is higher than that of parent compound by ΔTC = 138 K. The hydrogen embedded in Sm1.2Но0.8Fe17 crystal lattice increases the saturation magnetization (σS) at T = 300 K, but does not significantly affect σS at Т = 4.2 K. The ferrimagnetic structure is retained in magnetic fields up to 58 T in the parent compound, while, in the hydride, there is a spin-reorientation phase transition observed at 55 T. It is found that the parameter of the intersublattice exchange interaction decreases significantly in the hydride Sm1.2Ho0.8Fe17H4.4 (and in the nitride Sm1.2Ho0.8Fe17N2.4) which is associated with boosting of the unit-cell volume and distances between magnetic ions.



中文翻译:

Sm 1.2 Ho 0.8 Fe 17 Н x ( x  = 0; 4.4) 的合成、结构和磁性

基于稀土金属和铁的金属间化合物是迄今为止最有前途的永磁材料。在这项工作中,多组分化合物 Sm 1.2 Ho 0.8 Fe 17是通过感应熔化制备的。通过金属间化合物的直接氢化得到具有高氢含量的氢化物Sm 1.2 Ho 0.8 Fe 17 H 4.4。菱面体 Th 2 Zn 17型结构(空间群电阻3¯) 也是母体化合物和氢化物固有的。研究了氢化对Sm 1.2 Ho 0.8 Fe 17磁性能的影响。氢化物 Sm 1.2 Ho 0.8- Fe 17 H 4.4 的居里温度比母体化合物高 Δ T C  = 138 K。嵌入 Sm 1.2 Но 0.8 Fe 17晶格中的氢增加了饱和磁化强度 ( σ S ) T  = 300 K,但不会显着影响Т处的σ S = 4.2 K。在母体化合物中,亚铁磁结构保留在高达 58 T 的磁场中,而在氢化物中,在 55 T 处观察到自旋重定向相变。氢化物 Sm 1.2 Ho 0.8 Fe 17 H 4.4(以及氮化物 Sm 1.2 Ho 0.8 Fe 17 N 2.4)中的相互作用显着降低,这与晶胞体积和磁性离子之间距离的增加有关。

更新日期:2020-08-16
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